作者机构:
[Wangzhengqing; Liushan; Huyang; Xieyanshi; Duanxianzhe; Fengzhigang; Chenliang] Univ South China, Sch Nucl Resources Engn, Hengyang 421001, Hunan, Peoples R China.;[Huyang] Univ South China, Postdoctoral Res Stn Min Engn, Hengyang 421001, Hunan, Peoples R China.;[Huyang] Cooperat Innovat Ctr Nucl Fuel Cycle Technol & Eq, Hengyang 421001, Hunan, Peoples R China.;[Jiazhikun] Sinochem Petr Explorat & Prod Co Ltd, Beijing 100031, Peoples R China.
会议名称:
4th International Conference on Energy and Environmental Protection (ICEEP)
会议时间:
JUN 02-04, 2015
会议地点:
Shenzhen, PEOPLES R CHINA
会议主办单位:
[Huyang;Fengzhigang;Xieyanshi;Chenliang;Duanxianzhe;Wangzhengqing;Liushan] Univ South China, Sch Nucl Resources Engn, Hengyang 421001, Hunan, Peoples R China.^[Huyang] Univ South China, Postdoctoral Res Stn Min Engn, Hengyang 421001, Hunan, Peoples R China.^[Huyang] Cooperat Innovat Ctr Nucl Fuel Cycle Technol & Eq, Hengyang 421001, Hunan, Peoples R China.^[Jiazhikun] Sinochem Petr Explorat & Prod Co Ltd, Beijing 100031, Peoples R China.
关键词:
sandstone-type uranium deposit;chemical speciation of uranium;sequential chemical extraction;in-situ Leaching
摘要:
This paper presents a method of studying uranium speciation with six different hole depth and numbers from in-situ leaching sandstone-type uranium deposits by a sequential extraction procedure and demonstrates its application to sandstone uranium exploration. The chemical extraction procedure was modified from Tessier. The chemical speciation of uranium in samples was classified into six speciation: exchangeable ions, bound to carbonates, bound to sulfide-organic matter, bound to amorphous Fe-Mn oxides/bound to hydroxide, bound to sparry Fe-Mn oxides/bound to hydroxide and residual speciation. Studying the chemical speciation of uranium by method of sequential extraction show that the uranium distribution characteristics were significantly different whether they were in different samples or in the same sample. Therefore, a research on chemical speciation of Deposit behind the production is essential to reasonable evaluation of Deposit and guide the technology of in-situ leaching uranium Deposit. It also can rich the mineralization mechanism of sandstone-type uranium Deposit. The average amounts of bound to carbonates, exchangeable ions, bound to amorphous Fe-Mn oxides, residual speciation, bound to sulfide-organic matter and bound to sparry Fe-Mn oxides in order as 58.9%, 22.6%, 13.3%, 2.3%, 1.4% and 1.4%.
作者机构:
[马华龙; 唐振平; 陈胜; Zeng, Tao-Tao; 谢水波; 凌辉; 王劲松] Hunan Provincial Key Laboratory of Pollution Control and Resources Technology, University of South China, Hengyang, China;[谢水波] Key Discipline Laboratory for National Defence for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang, China
作者机构:
[潘伟] Key Laboratory of Mine Thermo-motive Disaster and Prevention, Ministry of Education, Liaoning Technical University, Fuxin, China;[杨月平] School of Nuclear Resources Engineering, University of South China, Hengyang, China;[潘伟; 李孜军; 吴超] School of Resources and Safety Engineering, Central South University, Changsha, China
通讯机构:
Key Laboratory of Mine Thermo-motive Disaster and Prevention, Ministry of Education, Liaoning Technical University, Fuxin, China
作者机构:
[李峰; 陈伟; 丁德馨] School of Nuclear Resource Engineering, University of South China, Hengyang, China;[李峰; 陈伟; 胡南; 丁德馨] Key Discipline Laboratory for National Defence for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang, China
通讯机构:
School of Nuclear Resource Engineering, University of South China, Hengyang, China
关键词:
含金硫精矿;金;微波焙烧;预处理;浸出率;表面形貌
摘要:
对难浸含金硫精矿进行微波焙烧,考察微波功率、矿量(即样品质量)和焙烧时间对样品质量损失率和浸出率的影响。结果表明:当微波功率为16 k W、焙烧时间为50 min、矿量为900 g时,样品质量损失率可达28.12%,浸出率可达71.56%,较原矿直接碘化浸出率(9.82%)有了大幅提高。利用XRD和SEM技术分析焙烧前后样品的成分和表面形貌,微波焙烧后的样品较原矿更为松散、多孔,更利于浸出。
摘要:
In order to reveal the nonlinear dynamics characteristics of unsteady self-heating process of sulfide ores, nine different kinds of sulfide ore samples from a pyrite mine in China were taken as experimental materials and their self-heating characteristics were measured in laboratory. Furthermore, the measured temperature was studied by integrating wavelet transform, nonlinear characteristic parameters extraction and fuzzy comprehensive evaluation. The results indicate that only the ore samples 1, 2, 6 and 9 have obvious self-heating phenomenon, and their self-heating initiative temperatures are 220 ℃, 239 ℃, 220 ℃ and 220 ℃,respectively, which means that they are difficult to produce self-heating under normal mining conditions. The correlation dimension of self-heating process is fraction and the maximum Lyapunov exponent is positive, which means that it is feasible to study the self-heating process based on chaotic dynamics theory. The nonlinearities of self-heating process of these four samples (ore samples 1, 2, 6 and 9) are 0.8227, 0.7521, 0.9401 and 0.8827 respectively and the order of the samples according to these results is: sample 6,sample 9, sample 1, sample 2, which is consistent with the measured results of self-heating characteristics. Therefore, the nonlinearity method can be used to evaluate the self-heating tendency of sulfide ores, and it is an effective verification of the reliability of measured results.