[Lin, Hang; Liu, Taoying; Cao, Ping; Pu, Chengzhi] Cent S Univ, Sch Resources & Safety Engn, Changsha 410083, Hunan, Peoples R China.;[Liu, Taoying; Pu, Chengzhi] Univ South China, Nucl Resource Coll Engn, Hengyang 421001, Hunan, Peoples R China.
[Liu, Taoying] Cent S Univ, Sch Resources & Safety Engn, Changsha 410083, Hunan, Peoples R China.
Rock-like material;Multiple pre-existing flaws;Crack propagation and coalescence;Uniaxial compression
Fracture coalescence, which plays an important role in the behavior of brittle materials, is investigated by loading rock-like specimens with two and three pre-existing flaws made by pulling out the embedded metal inserts in the pre-cured period. Different geometries are obtained by changing the angle of the flaws with respect to the direction of loading and the spacing. With reference to the experimental observation of crack initiation and propagation from pre-existing flaws, the influences of the third pre-existing flaw on the cracking processes was analyzed. It was found during the test that: with the increase of the angle of the rock bridge, the rock specimen takes a turn from wing crack propagation failure to crack coalescence failure, and it will be more obvious with the increase of the prefabricated crack angle. According to the different geometries of pre-existing cracks, seven types of coalescence have been identified based on the nature of the cracks for the specimen with two pre-existing flaws. The multi-crack interaction results in the continuous degradation of the macroscopic mechanical properties of the rock mass. On one hand, it weakens the trend of relative sliding of the coplanar cracks, and on the other hand, it changed the coalescence patterns of the fractured specimen. The research reported here provides increased understanding of the fundamental nature of rock mass failure in compression. (C) 2014 Elsevier B.V. All rights reserved.
As an endogenous gaseous mediator, H2S exerts anti-oxidative, anti-inflammatory and cytoprotective effects in kidneys. This study was designed to investigate the protective effect of H2S against uranium-induced nephrotoxicity in adult SD male rats after in vivo effect of uranium on endogenous H2S formation was explored in kidneys. The levels of endogenous H2S and H2S-producing enzymes (CBS and CSE) were measured in renal homogenates from rats intoxicated by an intraperitoneally (i.p.) injection of uranyl acetate at a single dose of 2.5, 5 or 10 mg/kg. In rats injected i.p. with uranyl acetate (5 mg/kg) or NaHS (an H2S donor, 28 or 56 mu mol/kg) alone or in combination, we determined biochemical parameters and histopathological alteration to assess kidney function, examined oxidative stress markers, and investigated Nrf2 and NF-kappa B pathways in kidney homogenates. The results suggest that uranium intoxication in rats decreased endogenous H2S generation as well as CBS and CSE protein expression. NaHS administration in uranium-intoxicated rats ameliorated the renal biochemical indices and histopathological effects, lowered MDA accumulation, and restored GSH level and anti-oxidative enzymes activities like SOD, CAT, GPx and GST. NaHS treatment in uranium-intoxicated rats activated uranium-inhibited protein expression and nuclear translocation of transcription factor Nrf2, which increased protein expression of downstream target-Nrf2 genes HO-1, NQO-1, GCLC, and TXNRD-1. NaHS administration in uranium-intoxicated rats inhibited uranium-induced nuclear translocation and phosphorylation of transcription factor kappa B/p65, which decreased protein expression of target-p65 inflammatory genes TNF-alpha, iNOS, and COX-2. Taken together, these data implicate that H2S can afford protection to rat kidneys against uranium-induced adverse effects through induction of antioxidant defense by activating Nrf2 pathway and reduction of inflammatory response by suppressing NF-kappa B pathway. (C) 2015 Elsevier Ireland Ltd. All rights reserved.
[Ding, Dexin] Univ South China, Key Discipline Lab Natl Def Biotechnol Uranium Mi, Hengyang 421001, Peoples R China.
Amidoxime modified Aspergillus niger (AMAN) was prepared by the oximation reaction. The effects of the initial pH, contact time, initial U(VI) concentration and biosorbent dose on the adsorption of U(VI) ions from radioactive wastewater in U(VI) concentrations of less than 1 mg L−1 by AMAN and the raw Aspergillus niger (RAN) were investigated. The maximum adsorption efficiency by AMAN for the 0.5 mg L−1 U(VI) solution amounted to 98.85% under the optimum adsorption conditions, while the maximum adsorption efficiency by RAN was only 77.83%. The adsorption equilibrium data were found to be best fitted to Langmuir isotherm model, and the maximum biosorption capacity of AMAN for U(VI) was estimated to be 621 mg g−1 at 298 K. The biosorption kinetics followed the pseudo-second order model and intraparticle diffusion equation. The Gibbs free energy change (ΔG°), enthalpy change (ΔH°) and entropy change (ΔS°) showed that the adsorption process of U(VI) was spontaneous, feasible and endothermic. The SEM-EDS study indicated that much more U(VI) ions were adsorbed by AMAN than by RAN. FT-IR study showed that the –NH2 and N–OH groups of amidoxime were the dominant ones for binding UO22+ ions. Moreover, AMAN was found to have excellent selective adsorption capability of U(VI) due to amidoxime groups. The UO22+ ions adsorbed by AMAN could be desorbed using 0.1 M HCl, and the desorption efficiency reaching 87.28% at the 8th cycle of adsorption and desorption.
This paper investigates the influence of a flaw on crack initiation, the failure mode, deformation field and energy mechanism of the rock-like material under uniaxial compression. The results of laboratory test and numerical simulation demonstrate the flaw inclination effect can be classified into three groups: 0-30 degrees, 30-60 degrees and 75-90 degrees. The characteristic stresses increase as the flaw angle increases. The tensile cracks initiate from gentle flaws (alpha <= 30 degrees) and shear cracks appear at tips of steep flaws (alpha >= 45 degrees). The input energy, strain energy and dissipation energy of a specimen show approximate increasing trends as the flaw angle increases. (C) 2017 Elsevier Ltd. All rights reserved.
In order to develop an effective and economical method for removing U(VI) from the low concentration radioactive wastewater with the U(VI) concentration of less than 1 mg L<sup>-1</sup>, the biomass of Aspergillus niger was prepared and modified with ethylenediamine, and the biosorption of uranium from the low concentration radioactive wastewater by the unmodified and the modified biomasses was investigated in a batch system. The modified biomass exhibited the adsorption efficiency of 99.25 % for uranium under the optimum conditions that pH was 5.0, the contact time was 150 min, and the biosorbent dose was 0.2 g L<sup>-1</sup>. The adsorption fitted well to Langmuir isotherm, and the maximum sorption capacity of the modified biomass for U(VI) was determined to be 6.789 mg g<sup>-1</sup> which increased by 36.45 % compared with the unmodified biomass. The adsorption kinetics was better depicted by pseudo-second-order kinetic model. The Gibbs free energy change (ΔG <sup>0</sup>), enthalpy change (ΔH <sup>0</sup>), and entropy change (ΔS <sup>0</sup>) showed that the process of U(VI) adsorption was spontaneous, endothermic, and feasible. The changes in the groups, morphology, and the presence of U(VI) on the surface of the adsorbents which were characterized by FT-IR, SEM, and EDS, demonstrated that the U(VI) was successfully adsorbed onto the modified biomass. Moreover, the UO<inf>2</inf> <sup>2+</sup> absorbed on the modified biomass can be released by 0.1 mol L<sup>-1</sup> HNO<inf>3</inf> with high desorption efficiency of 99.21 %. The results show that the modified biomass can remove U(VI) from low concentration radioactive wastewater more effectively than the unmodified biomass.
Wang Qing-liang*;Ding De-xin;Hu E-ming;Yu Run-lan;Qiu Guan-zhou
Transactions of Nonferrous Metals Society of China,2008年18(6):1529-1532 ISSN：1003-6326
[Wang Qing-liang; Yu Run-lan; Qiu Guan-zhou] Cent S Univ, Sch Minerals Proc & Bioengn, Changsha 410083, Peoples R China.;[Ding De-xin; Wang Qing-liang; Hu E-ming] Univ S China, Key Discipline Lab Natl Def Biotechnol Uranium Mi, Hengyang 421001, Peoples R China.
[Wang Qing-liang] Cent S Univ, Sch Minerals Proc & Bioengn, Changsha 410083, Peoples R China.
24th International Mineral Processing Congress (IMPC)
SEP 24-28, 2008
Beijing, PEOPLES R CHINA
[Wang Qing-liang;Yu Run-lan;Qiu Guan-zhou] Cent S Univ, Sch Minerals Proc & Bioengn, Changsha 410083, Peoples R China.^[Wang Qing-liang;Ding De-xin;Hu E-ming] Univ S China, Key Discipline Lab Natl Def Biotechnol Uranium Mi, Hengyang 421001, Peoples R China.
sulfate reducing bacteria;in-situ leaching of uranium;radioactively contaminated groundwater;bioremediation
In the case of in-situ leaching of uranium, the primitive geochemical environment for groundwater is changed since leachant is injected into the water bearing uranium deposit. This increases the concentration of SO_4~(2-), uranium and other heavy metal ions and results in the groundwater contamination. The effects of pH values of the simulated solution on the reduction of SO_4~(2-) and the removal of uranium and other heavy metal ions by sulfate reducing bacteria(SRB) were studied. The results show that, when the pH value of the simulated solution is about 8, the reduction rate of SO_4~(2-) by SRB and the removal rate of uranium, Mn~(2+), Zn~(2+), Pb~(2+) and Fe~(2+) will reach their highest values. A bioremediation technique for remediation of groundwater in in-situ leaching uranium mine can be developed.