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Efficient electrochemical removal of uranium(VI) by ACM@Ni cathode: Performance and mechanism

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成果类型:
期刊论文
作者:
Wu, Xujia;Zhao, Xinyu;Chen, Lijie;Sun, Jing;Dai, Zhongran
通讯作者:
Dai, ZR
作者机构:
[Wu, Xujia; Dai, Zhongran; Chen, Lijie; Sun, Jing; Zhao, Xinyu] Univ South China, Key Discipline Lab Natl Def Biotechnol Uranium Min, Hengyang 421001, Peoples R China.
通讯机构:
[Dai, ZR ] U
Univ South China, Key Discipline Lab Natl Def Biotechnol Uranium Min, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
U(VI);Removal;Cathoder;Electroadsorption;Mechanism
期刊:
Journal of Radioanalytical and Nuclear Chemistry
ISSN:
0236-5731
年:
2025
页码:
1-10
基金类别:
science and technology innovation Program of Hunan Province [2023RC3170]; National Natural Science Foundation of China [52304189]; Scientific Research Fund of Hunan Provincial Education Department [21A0259, 22B0438]
机构署名:
本校为第一且通讯机构
院系归属:
核资源工程学院
摘要:
Herein, a novel composite cathode material of Ni foam supported by amidoxime cellulose microspheres (ACM@Ni) has been prepared. The removal rate of U(VI) can reach 95% within 4 h under the conditions of 298.15 K, pH = 4 and 1.2 V, which was 5 times faster than the physical adsorption. The adsorption data of U(VI) were consistent with the quasi-first-order kinetic and Freundlich isotherm model, revealing the multilayer chemisorption process of uranium on the ACM-5@Ni cathode. In addition, ACM-5@Ni electrode materials also have potential applic...

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