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Uranium speciation in sediments in microcosms before and after incubation under anoxic conditions

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成果类型:
期刊论文
作者:
Ding, Dexin*;Xu, Fei;Hu, Nan;Li, Shimi;Tan, Xiang;...
通讯作者:
Ding, Dexin
作者机构:
[Ding, Dexin; Li, Shimi; Li, Guangyue; Hu, Nan; Tan, Xiang; Xu, Fei] Univ South China, Key Discipline Lab Natl Deference Biotechnol Uran, Hengyang 421001, Hunan, Peoples R China.
通讯机构:
[Ding, Dexin] U
Univ South China, Key Discipline Lab Natl Deference Biotechnol Uran, Hengyang 421001, Hunan, Peoples R China.
语种:
英文
关键词:
Uranium speciation;Microcosm;Incubation;Anoxic condition;XAFS
期刊:
Journal of Radioanalytical and Nuclear Chemistry
ISSN:
0236-5731
年:
2015
卷:
303
期:
1
页码:
925-933
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51274124]; Key Project for Fundamental Science of National Defense [B3720132001]
机构署名:
本校为第一且通讯机构
院系归属:
核资源工程学院
摘要:
In order to verify whether the U(VI) in groundwater under anoxic conditions can be bioreduced, microcosms were prepared with the uranium contaminated groundwater and sediment, amended with ethanol, lactate and glucose, and incubated under anoxic conditions. After 121 days of incubation, uranium L3-edge X-ray absorption fine structure spectra analysis indicated that more than 40 % of the U(VI) was reduced to U(IV) in the amended microcosms, and the initial U(VI) which was bound to C- and P-containing ligands was no longer bound to C-containing l...

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