摘要:
An absorptive fungal strain for uranium adsorption which is named Q5, was isolated from the drainage of a uranium mine in South China. The morphological, physiological and phylogenetic characterizations of the strain Q5 were investigated. The results showed that, the strain Q5 identified as Penicillium funiculosum (99 % similarity in gene sequence). Furthermore, the adsorption performance of P. funiculosum was greatly improved by the mutational method that combined hydroxylamine hydrochloride and UV light. The results showed that the adsorption capacity of the mutated P. funiculosum for U(VI) was obviously better than the non-mutational one at pH 2.0–9.0.
作者机构:
[叶勇军; 赵娅利; 谢东; 李向阳; 钟永明; 王立恒] School of Environment Protection and Safety Engineering, University of South China, Hengyang, China;[叶勇军; 丁德馨] Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang, China
通讯机构:
Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang, China
作者机构:
[叶勇军; 王立恒; 曹雅琴; 赵娅利; 范楠彬] School of Environmental Protection and Safety Engineering, University of South China, Hengyang, China;[丁德馨] Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang, China
通讯机构:
Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang, China
期刊:
Journal of Radioanalytical and Nuclear Chemistry,2014年299(3):1903-1909 ISSN:0236-5731
通讯作者:
Ding, Dexin
作者机构:
[Ding, Dexin; Li, Guangyue; Hu, Nan; Xin, Xin; Fu, Pingkun] Univ South China, Key Discipline Lab Natl Def Biotechnol Uranium Mi, Hengyang 421001, Peoples R China.;[Li, Le] Univ South China, Sch Publ Hlth, Hengyang 421001, Peoples R China.
通讯机构:
[Ding, Dexin] U;Univ South China, Key Discipline Lab Natl Def Biotechnol Uranium Mi, Hengyang 421001, Peoples R China.
关键词:
Sodium feldspar;U(VI) ion adsorption;Low concentration aqueous solution;Kinetic;Water treatment
摘要:
The raw sodium feldspar (RSF) is activated with the concentrated sulfuric acid solution and the acid activated sodium feldspar (AASF) is obtained. The results obtained from the mercury intrusion method show that the acidification can increase the porosity and the specific surface area. The effects of the initial pH, contact time and ambient temperature on the adsorption of U(VI) ions are investigated in a batch process. The adsorption efficiency amounts to the highest at pH 6 and the adsorption equilibrium is reached in 600 min. The pseudo-second-order model is found to be more suitable for the adsorption process than the pseudo-first-order model and intra-particle model, indicating that the chemical adsorption is the predominant step for the adsorption process. Langmuir model is found to describe the adsorption process better than Freundlich model. This proves that the main form of U(VI) ions attached to RSF and AASF is the monolayer coverage. The thermodynamic parameters prove that the adsorption process is a spontaneous endothermic one. It was also found that acid activated treatment can help increase the adsorption rate and capacity. The results show that RSF and AASF can be used as a novel low cost adsorbent for removal of U(VI) ions from the low concentration aqueous solution.
作者机构:
[李广悦; 扶海鹰; 叶勇军; 丁德馨; 宋键斌; 胡南; 王永东] Key Discipline Lab for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang 421001, China
通讯机构:
Key Discipline Lab for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, China
关键词:
铀矿;柱浸;堆浸;数学模型;浸出率
摘要:
针对铀矿堆浸生产中矿堆不同高度上的铀金属浸出存在的延迟现象,采用理论分析和室内柱浸试验研究铀矿浸出试验柱不同高度上铀金属浸出的规律。理论分析将铀矿浸出试验柱沿柱高划分为若干个高度足够小且相等的单元体,使其中单个铀矿石颗粒的浸出符合收缩未反应核扩散控制系统模型,且任意1个单元体内所有铀矿石颗粒反应均匀,不存在延迟现象,进而以1个单元体为目标,根据溶浸剂质量守恒原理,并考虑初始溶浸剂浓度的变化,建立铀矿浸出试验柱不同高度上铀金属浸出的数学模型。采用颗粒半径为2.5 mm 的铀矿石进行串联柱浸试验。然后,采用数学模型对柱浸试验结果进行计算,并将模型计算结果与柱浸试验结果进行比较。研究结果表明:试验柱不同高度上铀金属浸出率存在较大差别,且模型计算值与柱浸试验值具有相同的变化趋势,表明该数学模型能较好地反映铀矿浸出试验柱不同高度上铀金属浸出的延迟规律,可为预测铀矿堆浸不同高度上的浸出率提供重要参考。
通讯机构:
Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang, China
作者机构:
[王立恒; 钟永明; 范楠彬; 赵娅利; 叶勇军] School of Environment Protection and Safety Engineering, University of South China, Hengyang, China;[叶勇军; 丁德馨] Key Discipline Lab for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang, China
通讯机构:
School of Environment Protection and Safety Engineering, University of South China, Hengyang, China
作者机构:
[李广悦; 王永东; 扶海鹰; 宋键斌; 胡南; 丁德馨; 叶勇军] Key Discipline Lab for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang 421001, China
通讯机构:
Key Discipline Lab for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, China
摘要:
基于微生物诱导碳酸钙沉积的岩土工程加固技术是一种环境友好的新技术。碳酸钙矿化菌是该技术应用的前提。为获得具有诱导碳酸钙沉积能力的菌株,采用选择性富集培养、平板分离方法从土壤中分离得到了一株具有尿素分解能力的菌株,细菌诱导产生的沉积物检测结果表明该菌株具有诱导碳酸钙沉积能力。通过形态学、革兰氏染色和16 S rDNA序列同源性分析鉴定该菌株为巴斯德芽孢杆菌。
作者机构:
[殷杰; 谢红艳; 胡劲松] School of Pharmacy and Biological Sciences, University of South China, Hengyang, China;[殷杰; 丁德馨] Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang, China
通讯机构:
School of Pharmacy and Biological Sciences, University of South China, Hengyang, China
作者机构:
[胡鄂明; 史文革; 李乾; 王清良; 丁德馨] School of Nuclear Resources Engineering, University of South China, Hengyang 421001, China;[刘学端; 马丽媛] School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China;[李乾; 丁德馨] Key Discipline Lab. for National Defence of Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang 421001, China
通讯机构:
School of Minerals Processing and Bioengineering, Central South University, China
作者机构:
[李峰; 胡南; 彭志成; 陈伟; 丁德馨] Key Discipline Lab. for National Defence for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang 421001, China;[李峰; 彭志成; 陈伟; 丁德馨] School of Nuclear Resource Engineering, University of South China, Hengyang 421001, China
通讯机构:
Key Discipline Lab. for National Defence for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, China