作者:
Wang YongJian;Nie JiangTao;Lin JinRong;Pang YaQing;Wang ZhengQing;...
期刊:
岩石学报,2022年38(9):2865-2888 ISSN:1000-0569
作者机构:
[Nie JiangTao; Lin JinRong; Wang YongJian; Pang YaQing] Beijing Res Inst Uranium Geol, Beijing 100029, Peoples R China.;[Qin KeZhang; Wang YongJian] Chinese Acad Sci, Inst Geol & Geophys, Key Lab Mineral Resources, Beijing 100029, Peoples R China.;[Qin KeZhang; Wang YongJian] Univ Chinese Acad Sci, Coll Earth & Planetary Sci, Beijing 100049, Peoples R China.;[Wang ZhengQing] Univ South China, Sch Nucl Resources Engn, Hengyang 421001, Peoples R China.
通讯机构:
Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang, China
作者机构:
南华大学铀矿冶生物技术国防重点学科实验室,衡阳421001;南华大学极贫铀资源绿色开发技术湖南省重点实验室,衡阳421001;[丁德馨; 张丹; 张悦; 马建洪; 谭国炽; 胡南; 张辉; 张琪] Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang, 421001, China, Hunan Province Key Laboratory of Green Development Technology for Extremely Low Grade Uranium Resources, Hengyang, 421001, China
通讯机构:
[Ding, D.] K;[Ding, D.] H;Hunan Province Key Laboratory of Green Development Technology for Extremely Low Grade Uranium ResourcesChina;Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, China
作者机构:
[胡南; 陈雪; 张辉; 李艾书; 李广悦; 王永东; 丁德馨] Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang;421001, China;[胡南; 陈雪; 张辉; 李艾书; 李广悦; 王永东; 丁德馨] 421001, China
作者机构:
[伍随意; 胡俊毅; 贺俊钦; 王国华; 荣丽杉; 金远远] Hunan Provincial Key Laboratory of Pollution Control and Resources Technology, University of South China, Hengyang;421001, China;[李仕友] Key Discipline Laboratory for National Defence for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang;[伍随意; 李仕友; 胡俊毅; 贺俊钦; 王国华; 荣丽杉; 金远远] 421001, China
通讯机构:
[Li, S.] K;Key Discipline Laboratory for National Defence for Biotechnology in Uranium Mining and Hydrometallurgy, China
作者机构:
[Huang, Tao; Zhou, Lulu; Liu, Long-Fei] Changshu Inst Technol, Sch Mat Engn, Changshu 215500, Peoples R China.;[Huang, Tao] Changshu Inst Technol, Suzhou Key Lab Funct Ceram Mat, Changshu 215500, Peoples R China.;[Xie, Juan] Changshu Inst Technol, Sch Text Garment & Design, Changshu 215500, Peoples R China.;[Huang, Tao] China Univ Min & Technol, Sch Chem Engn & Technol, Xuzhou 221116, Peoples R China.;[Zhang, Shu-Wen] Univ South China, Nucl Resources Engn Coll, Hengyang 421001, Peoples R China.
通讯机构:
[Tao Huang; Juan Xie] S;School of Materials Engineering, Changshu Institute of Technology, Changshu 215500, China<&wdkj&>Suzhou Key Laboratory of Functional Ceramic Materials, Changshu Institute of Technology, Changshu 215500, China<&wdkj&>School of Chemical Engineering & Technology, China University of Mining and Technology, Xuzhou 221116, China<&wdkj&>School of Textile, Garment, and Design, Changshu Institute of Technology, 215500, China
关键词:
Quadrivalent cerium;Laurylsulfonate green rust;Adsorption mechanism;Rare earth element;Synthesis optimization
摘要:
The layered laurylsulfonate intercalated green rust(lauryl-S GR) was synthesized to evaluate the influence of synthesis parameters and aqueous conditions on the adsorption of CeⅣ.The maximum adsorption capacity of 305.58 mg/g by lauryl-S GR was predictably obtained.The pseudo-first-order kinetic model was appropriate in fitting the whole uptake process in a weak acid environment.Three isotherm models including Langmuir, Freundlich, and Tempkin were all reliable in depicting the isotherm adsorption process.The maximum monolayer adsorption capacity of lauryl-S GR towards CeⅣ was 315.46 mg/g.Ce species including CeO and Ce2O3 besides CeO2 were matched in the XPS distribution, directly indicating the reduction reaction brought by FeⅡ in the GR occurred to hydrated CeⅣ ions during the adsorption.Nano-sized Ce particles attached to the lauryl-S GRs after the adsorption experiments were observed in the morphological characterization.Flocculated materials were formed on the surface of the lauryl-S GR at a pH of 7, which further reduced the active sites and disrupted the continuous uptake of CeⅣ to the lauryl-S GR.This study expands the application of GRs and supplies an ideal iron-based material for the construction of the affiliated recovery pathway to the traditional separation of Ce.
作者机构:
[刘清; 邓真宁] Hunan Province Key Laboratory of Pollution Control and Resources Reuse Technology, University of South China, Hengyang;Hunan;421001, China;[滑熠龙] Key Discipline Laboratory for National Defence for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang;[招国栋] School of Resource & Environment and Safety Engineering, University of South China, Hengyang
作者机构:
[莫官海; 谢水波; Zeng, Taotao; 刘迎九] Hunan Province Key Laboratory of Pollution Control and Resource Reuse Technology, University of South China, Hengyang;Hunan;421001, China;Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang;[莫官海; 谢水波; Zeng, Taotao; 刘迎九] Hunan
通讯机构:
Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, Hunan Province Key Laboratory of Green Development Technology for Extremely Low Grade Uranium Resources, University of South China, Hengyang, China
作者机构:
[刘红娟; 吴仁杰] Institute of Nuclear Science and Technology, University of South China, Hengyang;Hunan;421001, China;[谢水波] Key Discipline Laboratory for National Defence for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang;[刘迎九] Hunan Province Key Laboratory of Pollution Control and Resources Reuse Technology, University of South China, Hengyang
通讯机构:
[Xie, S.-B.] K;Key Discipline Laboratory for National Defence for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang, Hunan, China
期刊:
北京理工大学学报,2018年38(3):300-304 and 312 ISSN:1001-0645
作者机构:
[宁志刚; 郝光鹏; 程雄; 沈文斌] College of Electrical Engineering, University of South China, Hengyang;Hunan;421001, China;[丁德馨] School of Nuclear Resource Engineering, University of South China, Hengyang;[宁志刚; 郝光鹏; 程雄; 沈文斌; 丁德馨] Hunan
作者机构:
[潘旺; Zeng J.; 贺明强; 余立军; Lin Y.; 李春光] School of Nuclear Resource Engineering, University of South China, Hengyang, 421001, China;[林煜臻] School of Environmental and Safety Engineering, University of South China, Hengyang, 421001, China
通讯机构:
[Liu, Z.] S;School of Environmental and Safety Engineering, University of South China, Hengyang, China