作者机构：
[Liu, Bing] Univ South China, Hengyang 421001, Peoples R China.;[Wang, Hongqing; Cui, Wenbin] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.;[Zhou, Jianliang] Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Peoples R China.
通讯机构：
[Hongqing Wang] S;School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China<&wdkj&>Author to whom correspondence should be addressed.
摘要：
Developing a fluorescent probe for UO(2)(2+), which is resistant to interference from other ions such as Cu(2+) and can be applied in acidic and high-water systems, has been a major challenge. In this study, a "turn-off" fluorescent probe for triamine-modified flavonoid derivatives, 2-triphenylamine-3-hydroxy-4H-chromen-4-one (abbreviated to HTPAF), was synthesized. In the solvent system of dimethyl sulfoxide:H(2)O (abbreviated to DMSO:H(2)O) (v/v = 5:95 pH = 4.5), the HTPAF solution was excited with 364 nm light and showed a strong fluorescence emission peak at 474 nm with a Stokes shift of 110 nm. After the addition of UO(2)(2+), the fluorescence at 474 nm was quenched. More importantly, there was no interference in the presence of metal ions (Pb(2+), Cd(2+), Cr(3+), Fe(3+), Co(2+), Th(4+), La(3+), etc.), especially Cu(2+) and Al(3+). It is worth noting that the theoretical model for the binding of UO(2)(2+) to HTPAF was derived by more detailed density functional theory (DFT) calculations in this study, while the coordination mode was further verified using HRMS, FT-IR and (1)HNMR, demonstrating a coordination ratio of 1:2. In addition, the corresponding photo-induced electron transfer (PET) fluorescence quenching mechanism was also proposed.
