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A Novel Triphenylamine-Based Flavonoid Fluorescent Probe with High Selectivity for Uranyl in Acid and High Water Systems

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成果类型:
期刊论文
作者:
Liu, Bing;Cui, Wenbin;Zhou, Jianliang;Wang, Hongqing
通讯作者:
Hongqing Wang
作者机构:
[Liu, Bing] Univ South China, Hengyang 421001, Peoples R China.
[Wang, Hongqing; Cui, Wenbin] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
[Zhou, Jianliang] Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Peoples R China.
通讯机构:
[Hongqing Wang] S
School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China<&wdkj&>Author to whom correspondence should be addressed.
语种:
英文
关键词:
UO22+;triphenylamine;flavonoid;turn off;fluorescent probe
期刊:
Sensors
ISSN:
1424-3210
年:
2022
卷:
22
期:
18
页码:
6987-
基金类别:
This research received no external funding.
机构署名:
本校为第一机构
院系归属:
化学化工学院
核科学技术学院
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摘要:
Developing a fluorescent probe for UO22+, which is resistant to interference from other ions such as Cu2+ and can be applied in acidic and high-water systems, has been a major challenge. In this study, a "turn-off" fluorescent probe for triamine-modified flavonoid derivatives, 2-triphenylamine3-hydroxy-4H-chromen-4-one (abbreviated to HTPAF), was synthesized. In the solvent system of dimethyl sulfoxide:H2O (abbreviated to DMSO:H2O) (v/v = 5:95 pH = 4.5), the HTPAF solution was excited with 364 nm light and showed a strong fluorescence emission peak at 474 nm with a Stokes shift of 110 nm. Afte...

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