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Efficient reduction of uranyl under aerobic conditions by sodium and potassium co-doped carbon nitride

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成果类型:
期刊论文
作者:
Li, Yuehuan;Shi, Lang;Mao, Yu;Zhang, Yu;Wang, Hongqing
通讯作者:
Wang, Hongqing(hqwang@usc.edu.cn)
作者机构:
[Wang, Hongqing; Shi, Lang; Zhang, Yu; Li, Yuehuan] Univ South China, Coll Chem & Chem Engn, Hunan Key Lab Design & Applicat Actinide Complexes, Hengyang 421001, Hunan, Peoples R China.
[Mao, Yu] Hunan Univ, Coll Chem & Chem Engn, Joint Int Ctr CO2 Capture & Storage iCCS, Prov Hunan Key Lab Costeffect Utilizat Fossil Fuel, Changsha 410082, Peoples R China.
通讯机构:
[Hongqing Wang] H
Hunan Key Laboratory for the Design and Application of Actinide Complexes, College of Chemistry and Chemical Engineering, University of South China, Hengyang, Hunan 421001, PR China
语种:
英文
关键词:
Aerobic conditions;Benzyl alcohol;CD-NaK;Photoreduction;U(VI)
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2022
卷:
446
页码:
136872
基金类别:
This work was financially supported by National Natural Science Foundation of China (No. 22176084 and 2210060957); Postgraduate Scientific Research Innovation Project of University of South China [213YXC005].
机构署名:
本校为第一机构
院系归属:
化学化工学院
摘要:
It is still a challenge for photocatalytic reduction of uranyl and maintaining catalyst stability under aerobic conditions. Herein, a catalyst of sodium–potassium co-doped g-C3N4 (CD-NaK) was obtained to remove Hexavalent Uranium (U(VI)) by photocatalytic reduction under aerobic conditions. And the CD-NaK was characterized by XRD, XPS and other methods. Furthermore, DFT calculations and XRD revealed that Na was doped in-plane while K was doped in-plane and interlayer, enhancing holes and electrons separation performance. Moreover, the removal ...

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