Aneutronic fusion reactions such as proton–boron fusion could efficiently produce clean energy with quite low neutron doses. However, as a consequence, conventional neutron spectral methods for diagnosing plasma ion temperature would no longer work. Therefore, finding a way to probe the ion temperature in aneutronic fusion plasmas is a crucial task. Here, we present a method to realize ultrafast in situ probing of 11B ion temperature for proton–boron fusion by Doppler broadening of the nuclear resonance fluorescence (NRF) emission spectrum. T...