Synthesis and characterization of 5-(trifluoromethyl)tetrazol-based energetic salts

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成果类型：

期刊论文

作者：

Deng, Jiawen;Lin, Lukang;Zhang, Yahan;Yao, Xu;Zhang, Jun;...

通讯作者：

Yi, Wenbin;Zheng, X;Lin, Jin-Hong;Xiao, JC;Yi, WB

作者机构：

[Yi, Wenbin; Zheng, Xing; Deng, Jiawen; Yi, WB; Yao, Xu; Zheng, X] Univ South China, Inst Pharm & Pharmacol, Hengyang Med Sch, Hengyang 421001, Hunan, Peoples R China.

[Lin, Jin-Hong; Lin, JH; Xiao, Ji-Chang; Zhang, Yahan] Univ Chinese Acad Sci, Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Fluorine & Nitrogen Chem & Adv Mat, 345 Lingling Lu, Shanghai 200032, Peoples R China.

[Zheng, Xing; Zhang, Jun; Zheng, X] Hunan Vocat Coll Sci & Technol, Dept Pharm, Third Zhongyi Shan Rd, Changsha 410004, Hunan, Peoples R China.

[Yi, WB; Yi, Wenbin; Lin, Lukang] Nanjing Univ Sci & Technol, Coll Chem Engn, 200 Xiaolingwei, Nanjing 210094, Peoples R China.

通讯机构：

[Yi, WB ] N

[Yi, WB; Xiao, JC ; Lin, JH; Zheng, X ] U

Univ South China, Inst Pharm & Pharmacol, Hengyang Med Sch, Hengyang 421001, Hunan, Peoples R China.

Univ Chinese Acad Sci, Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Fluorine & Nitrogen Chem & Adv Mat, 345 Lingling Lu, Shanghai 200032, Peoples R China.

Hunan Vocat Coll Sci & Technol, Dept Pharm, Third Zhongyi Shan Rd, Changsha 410004, Hunan, Peoples R China.

语种：

英文

关键词：

Energetic salts;Insensitive;Trifluoromethyl

期刊：

Journal of Fluorine Chemistry

ISSN：

0022-1139

年：

2025

卷：

283

页码：

110427

DOI：

10.1016/j.jfluchem.2025.110427

基金类别：

CRediT authorship contribution statement Jiawen Deng: Writing – original draft, Methodology, Investigation, Formal analysis. Lukang Lin: Investigation. Yahan Zhang: Methodology, Investigation, Formal analysis. Xu Yao: Project administration. Jun Zhang: Investigation. Jin-Hong Lin: Supervision, Project administration, Investigation. Wenbin Yi: Methodology, Formal analysis. Xing Zheng: Supervision, Formal analysis. Ji-Chang Xiao: Writing – review & editing, Investigation, acquisition, Conceptualization.

机构署名：

本校为第一且通讯机构

院系归属：

药学与生物科学学院

摘要：

Two types of 5-trifluoromethyl tetrazole-based energetic salts were successfully synthesized from trifluoroacetamide and sodium azide. The synthetic approach is characterized by its simplicity and safety. The X-ray diffraction analysis reveals the presence of both intermolecular and intramolecular hydrogen bonding within the crystal lattice of energetic salts. The synthesized compound 4 demonstrated notable physical properties, including high densities (1.64 g cm -3 ), great thermal stability (with decomposition temperatures of 167 °C), and ex...

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Synthesis and characterization of 5-(trifluoromethyl)tetrazol-based energetic salts

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