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Synthesis and characterization of a novel core-shell magnetic nanocomposite via surface-initiated RAFT polymerization for highly efficient and selective adsorption of uranium(VI)

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成果类型:
期刊论文
作者:
Dai, Zhongran;Zhang, Hui;Sui, Yang;Ding, Dexin*;Hu, Nan;...
通讯作者:
Ding, Dexin
作者机构:
[Ding, Dexin; Zhang, Hui; Li, Le; Dai, Zhongran; Hu, Nan; Wang, Yongdong] Univ South China, Key Discipline Lab Natl Def Biotechnol Uranium Mi, Hengyang 421001, Peoples R China.
[Sui, Yang] Hunan Taohuajiang Nucl Power Co Ltd, Yiyang 413000, Peoples R China.
通讯机构:
[Ding, Dexin] U
Univ South China, Key Discipline Lab Natl Def Biotechnol Uranium Mi, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
Uranium(VI);Magnetic nanocomposite;Surface-initiated RAFT polymerization;Adsorption
期刊:
Journal of Radioanalytical and Nuclear Chemistry
ISSN:
0236-5731
年:
2018
卷:
316
期:
1
页码:
369-382
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [U1401231, 51704170, 11405081]; Development Program for Science and Technology for National Defense [B3720132001]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2017M612569]; Research Foundation of Education Bureau of Hunan Province [16C1386]
机构署名:
本校为第一且通讯机构
院系归属:
核资源工程学院
摘要:
In this work, the nanoparticles possessing a macro-initiator (MNPs@SCSOEt) were firstly obtained by surface-initiated RAFT polymerization. The structure of the nanocomposite was characterized by FT-IR, SEM, TEM, TGA, XPS and VSM. The effects of pH, contact time, initial uranium concentrations, coexisting ions and temperature on the U(VI) adsorption by MNPs@PAO were investigated in detail. The adsorption process was found to be in good agreement with pseudo-second order kinetic model and Langmuir adsorption isotherm model. The maximum adsorption...

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