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Cooperative Capture of Uranyl Ions by a Carbonyl‐Bearing Hierarchical‐Porous Cu–Organic Framework

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成果类型:
期刊论文
作者:
Prof. Dr. Xiao-Feng Wang;Yangyang Chen;Li-Ping Song;Dr. Zhen Fang;Jian Zhang;...
通讯作者:
Prof. Dr. Xiao-Feng Wang<&wdkj&>Prof. Dr. Ying-Wu Lin<&wdkj&>Prof. Dr. Yue-Biao Zhang<&wdkj&>Prof. Dr. João Rocha
作者机构:
[Prof. Dr. Yue-Biao Zhang] School of Physical Science and Technology, ShanghaiTech University, 393 Middle Huaxia Road, Pudong, Shanghai, China
[Dr. Zhen Fang] College of Chemistry and Materials Science, Anhui Normal University, No.1, East Beijing Road, Wuhu, 241000 Anhui, China
[Dr. Fanian Shi; Prof. Dr. João Rocha] Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, Santiago Campus, Aveiro, 3810-193 Portugal
[Yangyang Chen; Li-Ping Song; Jian Zhang; Prof. Dr. Ying-Wu Lin; Dr. Yunkai Sun] School of Chemistry and Chemical Engineering, University of South China, No. 28, Changsheng Xi Road, Hengyang, 421001 Hunan, China
[Prof. Dr. Xiao-Feng Wang] School of Chemistry and Chemical Engineering, University of South China, No. 28, Changsheng Xi Road, Hengyang, 421001 Hunan, China<&wdkj&>Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, Santiago Campus, Aveiro, 3810-193 Portugal
通讯机构:
[Prof. Dr. Xiao-Feng Wang; Prof. Dr. Ying-Wu Lin; Prof. Dr. Yue-Biao Zhang] S
[Prof. Dr. João Rocha] D
School of Physical Science and Technology, ShanghaiTech University, 393 Middle Huaxia Road, Pudong, Shanghai, China<&wdkj&>Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, Santiago Campus, Aveiro, 3810-193 Portugal<&wdkj&>School of Chemistry and Chemical Engineering, University of South China, No. 28, Changsheng Xi Road, Hengyang, 421001 Hunan, China<&wdkj&>Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, Santiago Campus, Aveiro, 3810-193 Portugal<&wdkj&>School of Chemistry and Chemical Engineering, University of South China, No. 28, Changsheng Xi Road, Hengyang, 421001 Hunan, China
语种:
英文
关键词:
Adsorptionsmechanismen;Metall-organische Gerüste;Poröse Materialien;Einkristallstrukturen;Uranyl-Sorption
期刊:
Angewandte Chemie
ISSN:
0044-8249
年:
2019
卷:
131
期:
52
页码:
18984-18988
基金类别:
National Natural Science Foundation of China#&#&#11375082 Scientific Research Foundation for Returned Scholars of Ministry of Education Fundação para a Ciência e a Tecnologia#&#&#UID/CTM/50011/2019
机构署名:
本校为通讯机构
院系归属:
化学化工学院
摘要:
AbstractTo efficiently capture the toxic uranyl ions (UO22+), a new hierarchical micro‐macroporous metal–organic framework was prepared under template‐free conditions, featuring interconnected multi‐nanocages bearing carbonyl groups derived from a semi‐rigid ligand. The material exhibits an unusually high UO22+ sorption capacity of 562 mg g−1, which occurs in an intriguing two‐steps process, on the macropore‐based crystal surface and in the inner nanocages. Notably, the latter is attributed to the cooperative interplay of the shrinkag...

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