期刊论文

Preparation and Characterization of T-Ac-Zn Metallohydrogel

中文

南华大学学报(自然科学版)

1673-0062

2018

32

1

92-96

10.19431/j.cnki.1673-0062.2018.01.016

31200140:国家自然科学基金 11475079:国家自然科学基金 15C1168:湖南省教育厅项目 2014XQD32:南华大学博士启动基金

本校为第一机构

通过简单的实验方法合成了凝胶因子T-Ac,并利用核磁84质3谱1等9实6验3方0法确证其结构.一定条件下,凝胶因子T-Ac可以和Zn2+自组装形成白色不透明的金属水凝胶T-Ac-Zn,该凝胶具有良好的刺激响应性.为了探索成胶机理,通过各种实验方法对金属水凝胶T-Ac-Zn进行了表征.

A low molecular weight gelatorT-Acwas synthesized by a simple method and its structure was proved by using NMR,mass spectrometry.Under moderate conditions,the gelator could self-assemble to form white and opaque metallohydrogel T-Ac-Zn in presence of Zn 2+.The prepared gel has excellent multiple responsiveness to external stimuli.To gain the mechanism of...