This paper describes a new method for determination of trace amounts of cerium. The principle of the method as follows:Ce (IV) system which was absent of fluorescence became a characteristic fluorescence of Ce (Ⅲ) ion by adding ascorbic acid into Ce (IV) system,and re - adding a certain concentration formaldehyde solution, the new system had greater fluorescence intensity of the sensitizer. Thereby a new method of an indirect determination of trace cerium (IV) ion was established. With this method Cerium (IV) ion concentration in th...