Study on isolation of the Angelica Sinensis polysaccharide (ASP) and its effects on anti-active oxygen free radical is presented in this paper. Isolation of ASP was extracted by hot water and alcohol precipitation,and purified by absorbent with Polyerde column membrane and eluted with hot water. Scavenge rate to O -· 2 and OH · with the crude ASP were 42.6% and 38.7% respectively;and with pure ASP were 35.7% and 29.4% respectively. The ASP was ...