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Facile synthesis of ceria nanospheres by Ce(OH)CO3 precursors

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成果类型:
期刊论文
作者:
Chen, Yong;Qiu, Changjun;Chen, Chunlin*;Fan, Xiangfang;Xu, Sibo;...
通讯作者:
Chen, Chunlin
作者机构:
[Fan, Xiangfang; Chen, Yong; Qiu, Changjun] Univ South China, Sch Mech Engn, Hengyang 421001, Peoples R China.
[Chen, Chunlin; Wang, Zhongchang; Chen, Yong] Tohoku Univ, WPI Res Ctr, Adv Inst Mat Res, Aoba Ku, Sendai, Miyagi 9808577, Japan.
[Xu, Sibo] Chongqing Univ, Coll Mat Sci & Engn, Chongqing 400044, Peoples R China.
[Guo, Weiwei] Chongqing Technol & Business Univ, Coll Environm & Biol Engn, Chongqing 400067, Peoples R China.
[Chen, Chunlin] Tohoku Univ, WPI Res Ctr, Adv Inst Mat Res, Aoba Ku, 2-1-1 Katahira, Sendai, Miyagi 9808577, Japan.
通讯机构:
[Chen, Chunlin] T
Tohoku Univ, WPI Res Ctr, Adv Inst Mat Res, Aoba Ku, 2-1-1 Katahira, Sendai, Miyagi 9808577, Japan.
语种:
英文
关键词:
Ce(OH)CO 3 precursor;CeO 2 sphere;Hydrothermal synthesis process;UV-shielding functionality
期刊:
Materials Letters
ISSN:
0167-577X
年:
2014
卷:
122
页码:
90-93
基金类别:
Challenging Exploratory ResearchMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [24656376]; Sasakawa Scientific Research Grant; JGC-S Foundation; construct program of the key discipline in HuNan province; [24760532]; [24686069]
机构署名:
本校为第一机构
院系归属:
机械工程学院
摘要:
Spherical Ce(OH)CO3 precursors were prepared via a facile and an efficient hydrothermal process without hard templates. X-ray diffraction (XRD) analysis reveals that the as-synthesized spherical precursors are composed of high-purity Ce(OH)CO3 with a hexagonal structure. After calcination at 573 K for 10 h, the spherical Ce(OH)CO3 precursors decompose into CeO2 nanospheres with a cubic fluorite structure. We also find that morphology of the Ce(OH)CO3 precursors and CeO2 nanospheres is modified significantly as a function of the different surfactants used in the hydrothermal process. When using...

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