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Uranium adsorption properties and mechanism of ZIF-8/microalgae composite adsorbent with crosslinked chitosan/tannic acid curing supported by quaternary phosphate ionic liquid

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成果类型:
期刊论文
作者:
Luo, Kaiwen;Wang, Qingliang;Xin, Qi;Lei, Zhiwu;Hu, Eming;...
通讯作者:
Wang, HQ
作者机构:
[Wang, HQ; Wang, Hongqiang; Wang, Qingliang; Luo, Kaiwen; Xin, Qi; Hu, Eming; Lei, Zhiwu] Univ South China, Sch Resource & Environm & Safety Engn, Hengyang 421001, Peoples R China.
[Wang, Hongqing] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
[Liang, Feng] Henan Univ Urban Construct, Sch Municipal & Environm Engn, Henan Key Lab Water Pollut Control & Rehabil Techn, Pingdingshan 467036, Peoples R China.
通讯机构:
[Wang, HQ ] U
Univ South China, Sch Resource & Environm & Safety Engn, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
Uranium;Ionic liquid;Chlorella pyrenoidosa;Adsorption;Selectivity
期刊:
Desalination
ISSN:
0011-9164
年:
2024
卷:
592
页码:
118079
基金类别:
Natural Science Foundation of Hunan Province [2024JJ5322]; Hunan Province major scientific and technological research [2023ZJ1060]; Post-graduate Scientific Research Innovation Project of Hunan Province [CX20240085]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
A novel chitosan/ZIF-8/algal powder (ZIF-8/CP/CT) composite adsorbent was synthesized for efficient adsorption of uranyl ions in seawater. The results demonstrate that ZIF-8/CP/CT exhibits excellent uranium adsorption performance within the pH range of 4.0-8.0, with an adsorption rate exceeding 89 %. Kinetic and thermodynamic experiments reveal that the theoretical maximum adsorption capacity of ZIF-8/CP/CT for U(VI) is 873 mg/g (308 K, pH = 6.0), indicating a spontaneous exothermic reaction. Mechanistic analysis reveals that the hydroxyl, amino, and P=O bonds on the surface of ZIF-8/CP/CT and...

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