期刊论文

Xiao, Jichang

英文

中国化学

1001-604X

2013

31

7

915-920

10.1002/cjoc.201300393

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21032006, 21172240]; 973 Program of ChinaNational Basic Research Program of China [2012CBA01200]; Chinese Academy of SciencesChinese Academy of Sciences

本校为其他机构

The copper-mediated trifluoromethylation of terminal alkynes with S-(trifluoromethyl)diarylsulfonium salt has been carefully investigated. The reactions proceeded smoothly to afford trifluoromethylated acetylenes in moderate to good yields. This approach is a convenient method to synthesize a variety of fu...

有 S-(trifluoromethyl ) diarylsulfonium 盐的终端炔属羟的调停铜的 trifluoromethylation 小心地被调查了。反应顺利继续了负担得起 trifluoromethylated 乙炔在对好收益中等。这条途径是一个方便方法综合许多功能的 trifluoromethylated 乙炔。