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An AIE+TICT activated colorimetric and ratiometric fluorescent sensor for portable, rapid, and selective detection of phosgene

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成果类型:
期刊论文
作者:
Hu, Qinghua*;Huang, Qiuxiang;Liang, Kexin;Wang, Yuyuan;Mao, Yu;...
通讯作者:
Hu, Qinghua;Wang, Hongqing
作者机构:
[Wang, Hongqing; Huang, Qiuxiang; Hu, Qinghua; Mao, Yu; Wang, HQ; Liang, Kexin; Wang, Yuyuan; Yin, Qiang] Univ South China, Sch Chem & Chem Engn, Hunan Key Lab Design & Applicat Actinide Complexe, 28 Changsheng West Rd, Hengyang 42001, Hunan, Peoples R China.
通讯机构:
[Hu, QH; Wang, HQ] U
Univ South China, Sch Chem & Chem Engn, Hunan Key Lab Design & Applicat Actinide Complexe, 28 Changsheng West Rd, Hengyang 42001, Hunan, Peoples R China.
语种:
英文
关键词:
Fluorescent sensors;AIE plus TICT;Phosgene;Colorimetric;Ratiometric
期刊:
Dyes and Pigments
ISSN:
0143-7208
年:
2020
卷:
176
页码:
108229
基金类别:
NSFCNational Natural Science Foundation of China [11804146, 11875161]; NSF of Hunan Province [2016JJ5003]; College Students' Innovation & Entrepreneurship Training Project of University of South China [2018XJXZ332]; Scientific Research Fund of Hunan Education Department [17B223]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
Colorless and highly toxic phosgene has long been considered to be a great menace to human health and national security. Excellent AIE + TICT characteristic ratiometric and colorimetric fluorescent sensor TPE-CI was constructed with the combination of the TICT based 3-benzo[d]imidazole-chromen-2-imine unit and AIE based tetraphenylethene (TPE) unit. TPE-CI can detect phosgene not only in organic solvent through a change from the TICT process to the AIE process, but also in solid-state through a new change from the AIE + TICT process to the AIE ...

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