Study on Screening Catalysts for the Synthesis of Acrolein Diethyl Acetal/Ammonia toward Pyridine and 3-Picoline

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作者信息关键词期刊信息会议信息基础信息归属信息摘要

成果类型：

期刊论文、会议论文

作者：

Luo, Cai-Wu*;Li, An;Liang, Shan;Lei, Bo;Wang, Zheng-Hao;...

通讯作者：

Luo, Cai-Wu

作者机构：

[Wang, Zheng-Hao; Luo, Cai-Wu; Lei, Bo] Univ South China, Sch Environm & Safety Engn, Hengyang 421001, Hunan, Peoples R China.

[Li, An] Hunan Inst Sci & Technol, Coll Chem & Chem Engn, Yueyang 414006, Hunan, Peoples R China.

[Liang, Shan] Univ South China, Sch Chem & Chem Engn, Hengyang, Hunan 421001, Peoples R China.

[Chao, Zi-Sheng] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China.

通讯机构：

[Luo, Cai-Wu] U

Univ South China, Sch Environm & Safety Engn, Hengyang 421001, Hunan, Peoples R China.

语种：

英文

期刊：

AIP Conference Proceedings

ISSN：

0094-243X

年：

2018

卷：

1986

期：

页码：

020001

会议名称：

THE 3RD INTERNATIONAL CONFERENCE ON MECHANICS, MATERIALS AND STRUCTURAL ENGINEERING 2018 (ICMMSE2018)

DOI：

10.1063/1.5047112

基金类别：

Hunan Provincial Natural Science Foundation of ChinaNatural Science Foundation of Hunan Province [2018JJ3427]; Educational Commission of Hunan Province [17C1361]; Doctoral Scientific Research Foundation of University of South China [2016XQD36]

机构署名：

本校为第一且通讯机构

院系归属：

化学化工学院

环境与安全工程学院

摘要：

In this work, series of catalysts like bimetallic oxides and supported ZSM-5 (acid and/or metal), were applied for the synthesis of pyridine and 3-picoline from acrolein diethyl acetal, water and ammonia in a fixed-bed reactor. The results showed that bimetallic oxides and alkaline catalysts exhibited extremely low catalytic activities whereas HZSM-5 had significantly better than MCM-41 and SBA-15. Among kinds of catalysts, the total yield of pyridine and 3-picoline over...

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Study on Screening Catalysts for the Synthesis of Acrolein Diethyl Acetal/Ammonia toward Pyridine and 3-Picoline

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