Mineral dissolution and erosion during the leaching of uranium-bearing sandstone have profound effects on the evolution of pore structure and uranium leaching rate. X-ray diffraction (XRD), scanning electron microscopy (SEM), and nuclear magnetic resonance (NMR) techniques were used to characterise mineral changes and pore structure evolution in samples. The results indicate that during the in situ leaching process, feldspar was transformed into clay minerals and quartz. Dolomite and calcite completely dissolved and formed a large amount of Ca 2+ , which increased the content of CaSO 4 . The C...