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Self-assembled Fe-doped PrBaCo2O5+δ composite cathodes with disorder transition region for intermediate-temperature solid oxide fuel cells

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成果类型:
期刊论文
作者:
Fu, Min;Lin, Xin;Tan, Lingui;Zhang, Ping;Xie, Haijiao;...
通讯作者:
Zetian Tao
作者机构:
[Lin, Xin; Tan, Lingui; Fu, Min; Tao, Zetian] Univ South China, Sch Resources Environm & Safety Engn, Hengyang 421001, Hunan, Peoples R China.
[Zhang, Ping] Univ South China, Sch Elect Engn, Hengyang 421001, Hunan, Peoples R China.
[Xie, Haijiao] Hangzhou Yanqu Informat Technol Co Ltd, Hangzhou 310003, Peoples R China.
通讯机构:
[Zetian Tao] S
School of Resources, Environment and Safety Engineering, University of South China, Hengyang, Hunan Province 421001, China
语种:
英文
关键词:
Functional ceramics;Hetero-interface;Composite cathode;Electrical conductivity relaxation;Oxygen reduction reaction
期刊:
International Journal of Hydrogen Energy
ISSN:
0360-3199
年:
2023
卷:
48
期:
40
页码:
15229-15237
基金类别:
National Natural Science Foundation of China [11875164]; Nat- ural Science Foundation of the Higher Education Institutions of Jiangsu Province [18KJA430017]
机构署名:
本校为第一机构
院系归属:
电气工程学院
摘要:
PrBa(Co1-xFex)2O5+d polymorphs (0.1 < x < 0.4, denoted as PBCF-x with Fe-doping level x) are reported and dual phase of cubic phase Pr0.5Ba0.5Co1_xFexO3_d and tetragonal phase PrBa(Co1-xFex)2O5+d are co-produced through an common sol-gel method. The co-generation of the dual-phases leads to the formation of abundant hetero-interfaces be-tween the neighboring crystal phases and the synergic effect demonstrates remarkably high oxygen adsorption and dissociation ability in the air. The density functional theory (DFT) calculation establishes that the existence of hetero-interfaces promotes oxygen ...

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