Motivated by the synthesized Cu4TiSe4 with ultralow room-temperature thermal conductivity [Angew. Chem., Int. Ed. 60, 9106 (2021)], we systematically investigate its thermoelectric (TE) properties via combining Boltzmann transport equations and first-principles calculations. The results show that the thermal conductivity of Cu4TiSe4 determined considering only three-phonon scattering is reduced by about 40% after including four-phonon scattering at room temperature, indicating the importance of four-phonon scattering in phonon transport. On the other hand, the coexistence of high dispersion an...