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Ligands modulated the variable binuclear Cd-2-SBUs and structures of four layered coordination frameworks

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成果类型:
期刊论文
作者:
Wang, Mengdie;Zhang, Jian;Sun, Yunkai*;Wei, Jing*;Tan, Chunhong;...
通讯作者:
Sun, Yunkai;Wang, Xiao-Feng;Wei, Jing
作者机构:
[Wang, Mengdie; Sun, Yunkai; Wang, Xiao-Feng; Zhang, Jian; Tan, Chunhong] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
[Sun, Yunkai; Wang, Xiao-Feng] Univ South China, Hunan Prov Engn Res Ctr Radioact Control Technol, Hengyang 421001, Peoples R China.
[Wei, Jing] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China.
通讯机构:
[Sun, YK; Wang, XF] U
[Wei, Jing] C
Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
Univ South China, Hunan Prov Engn Res Ctr Radioact Control Technol, Hengyang 421001, Peoples R China.
Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China.
语种:
英文
期刊:
CrystEngComm
ISSN:
1466-8033
年:
2020
卷:
22
期:
23
页码:
3965-3974
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11375082, 21403242, 11305086]; Hunan Province Engineering Research Center of Radioactive Control Technology in Uranium Mining and Metallurgy AMP; Hunan Province Engineering Technology Research Center of Uranium Tailings Treatment Technology, University of South China [2019YKZX1004]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
Four layered coordination polymers, namely, [Cd2(fuma)2(phen)2] (1), [Cd2(BDC)2(phen)2]·2DMF (2), [Cd2(NDC)2(phen)2]·0.5H2O (3), and [Cd2(NDC)2(bipy)2]·2DMF (4) have been synthesized under solvo-thermal conditions (fuma = fumaric acid, H2BDC = 1,4-benzenedicarboxylic acid, H2NDC = 1,4-naphthalenedicarboxylic acid, phen = 1,10-phenanthroline, bipy = 2,2′-bipyridine), which are composed of asymmetric/symmetric binuclear Cd2(RCOO)4(phen)2or Cd2(RCOO)4(bipy)2clusters as secondary building units (SBUs) linked by fuma2−, BDC2−, and NDC2−. Owin...

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