Extractive distillation experiment is an important comprehensive experiment for Chemical Engineering and Technology specialty. In the experiment, measurement of vapor-liquid equilibrium and experimental operation of extractive distillation were carried out, data regression of Aspen Plus software was used to regress the vapor-liquid equilibrium data to obtain the interaction parameters of UNIQUAC equation. Flash module was used to calculate the relative volatility of ethanol-water. RadFrac module was used to optimize the process parameters of extractive distillation and simulate the operation p...