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Synthesis of β-cyclodextrin functionalized silica gel and its application for adsorption of uranium(VI)

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成果类型:
期刊论文
作者:
Liu, Hui-Jun*;Jing, Peng-Fei;Liu, Xiu-Yun;Du, Ke-Jie;Sun, Yun-Kai
通讯作者:
Liu, Hui-Jun
作者机构:
[Sun, Yun-Kai; Liu, Xiu-Yun; Du, Ke-Jie; Liu, Hui-Jun; Jing, Peng-Fei] Univ South China, Coll Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
通讯机构:
[Liu, Hui-Jun] U
Univ South China, Coll Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
语种:
英文
关键词:
beta cyclodextrin;copper ion;iron;lanthanum;lead;magnesium ion;manganese;mercury;salicylamide;salicylamide silica gel beta cyclodextrin;silica gel;sodium ion;sorbent;unclassified drug;uranium;zinc ion;adsorption;analytical parameters;aqueous solution;Article;chemical binding;concentration (parameters);contact time;desorption;equilibrium time;Freundlich isotherm;infrared spectroscopy;kinetics;Langmuir isotherm;pH;scanning electron microscopy;synthesis;temperature;thermodynamics;X ray photoelectron spectroscopy
期刊:
Journal of Radioanalytical and Nuclear Chemistry
ISSN:
0236-5731
年:
2016
卷:
310
期:
1
页码:
263-270
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11375084]; Hunan Provincial Innovation Foundation For Postgraduate [CX2015B399]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
A novel β-cyclodextrin functionalized silica gel (SAM-Si-β-CD) was prepared with grafting β-cyclodextrin (β-CD) to silica gel (Si-β-CD) containing salicylamide. It was characterized using XPS, SEM and FT-IR techniques. Variables of batch experiments including pH, temperature, contact time, interfering ions were studied. Langmuir, Freundlich isotherm and kinetic models were suitable to describe the adsorption process. The results showed that the equilibrium adsorption capacity was found to be 6.45mgg−1 respectively at pH 4.5, equilibrium t...

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