期刊论文

Zhao, Yu-Bao;Shi, Wei-Qun

英文

INORGANIC CHEMISTRY

0020-1669

2018

57

8

4492-4501

10.1021/acs.inorgchem.8b00168

We are thankful for the support of the Science Challenge Project (JCKY2016212A504). We are also thankful for the support of the National Natural Science Foundation of China (Nos. 21577144, 21701178) and the Major Research Plan “Breeding and Transmutation of Nuclear Fuel in Advanced Nuclear Fission Energy System” of the Natural Science Foundation of China (91426302, 91326202). We appreciate the help from beamline 3W1A of Beijing Synchrotron Radiation Facility (BSRF) for X-ray single crystal measurements.

本校为第一且通讯机构

1 ), [(CH_(3))_(2)NH_(2)]UO_(2)(BTPCA) (2 ), [(CH_(3))_(2)NH_(2)]_(2)[UO_(2)(BTPCA)][UO_(2)(BTPCA)]·(H_(2)O)_(5.5) (3 ), [(CH_(3))_(2)NH_(2)]_(2)(UO_(2))_(2)(BTPCA)_(2)·(H_(2)O)_(3) (4 ), and [(CH_(3))_(2)NH_(2)]UO_(2)(BTPCA) (5 ), by the utilization of semirigid ligand 1,1′,1″-(benzene-1,3,5-triyl)tripiperidine-4-carboxylic acid (H_(3)BTPCA) and uranyl nitrate through solvothermal reactions. Single-crystal X-ray diffraction analysis reveals that the five compounds share a similar structure composition and local coordination mode to the exc...