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Novel Olefin-Linked Covalent Organic Framework with Multifunctional Group Modification for the Fluorescence/Smartphone Detection of Uranyl Ion

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成果类型:
期刊论文
作者:
Zhen, Deshuai;Liu, Chunlin;Deng, Qiuhui;Li, Le*;Grimes, Craig A.;...
通讯作者:
Li, Le;Yang, Shengyuan;Liu, Y
作者机构:
[Yang, Shengyuan; Yang, SY; Liu, Yu; Liu, Chunlin; Li, Le; Zhen, Deshuai; Deng, Qiuhui] Univ South China, Sch Publ Hlth, Hengyang Med Sch, Hunan Key Lab Typ Environm Pollut & Hlth Hazards, Hengyang 421001, Peoples R China.
[Cai, Qingyun; Liu, Yu; Liu, Chunlin; Zhen, Deshuai; Deng, Qiuhui] Hunan Univ, Sch Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Peoples R China.
[Grimes, Craig A.] Flux Photon Corp, Alpharetta, GA 30005 USA.
通讯机构:
[Yang, SY; Li, L; Liu, Y ] U
Univ South China, Sch Publ Hlth, Hengyang Med Sch, Hunan Key Lab Typ Environm Pollut & Hlth Hazards, Hengyang 421001, Peoples R China.
Hunan Univ, Sch Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Peoples R China.
语种:
英文
关键词:
amidoxime group;covalent organic frameworks;detection;knoevenagel;uranyl ion
期刊:
ACS Applied Materials & Interfaces
ISSN:
1944-8244
年:
2024
卷:
16
期:
21
页码:
27804-27812
基金类别:
National Natural Science Foundation of China [82204176, 12175103, 82073604]; National Natural Science Foundation of China [2023JJ50127, 2024JJ5345, WDZC-2023-AW-0322]; Natural Science Foundation of Hunan Province [CX20230993]; Program for Graduate Innovation Research of Hunan Province
机构署名:
本校为第一且通讯机构
院系归属:
公共卫生学院
摘要:
Monitoring and purification of uranium contamination are of great importance for the rational utilization of uranium resources and maintaining the environment. In this work, an olefin-linked covalent organic framework (GC-TFPB) and its amidoxime-modified product (GC-TFPB-AO) are synthesized with 3-cyano-4,6-dimethyl-2-hydroxypyridine (GC) and 1,3,5-tris(4-formylphenyl) benzene (TFPB) by Knoevenagel condensation. GC-TFPB-AO results in specificity for rapid fluorescent/smartphone uranyl ion (UO(2)(2+)) detection based on the synergistic effect of multifunctional groups (amidoxime, pyridine, and ...

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