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Synthesis and atomic-scale characterization of CeO2 nano-octahedrons

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成果类型:
期刊论文
作者:
Zhang, Manli;Chen, Yong*;Qiu, Changjun;Fan, Xiangfang;Chen, Chunlin;...
通讯作者:
Chen, Yong
作者机构:
[Fan, Xiangfang; Chen, Yong; Zhang, Manli; Qiu, Changjun] Univ South China, Sch Mech Engn, Hengyang 421001, Peoples R China.
[Chen, Chunlin; Wang, Zhongchang] Tohoku Univ, Adv Inst Mat Res, Aoba Ku, Sendai, Miyagi 980, Japan.
通讯机构:
[Chen, Yong] U
Univ South China, Sch Mech Engn, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
Ceria;Hydrothermal method;Nano-octahedron;Atomic-resolution imaging
期刊:
Physica E-Low-Dimensional Systems & Nanostructures
ISSN:
1386-9477
年:
2014
卷:
64
页码:
218-223
基金类别:
Construct Program of the Key Discipline of Hunan province; National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11332013]; JGC-S Foundation; Kurata Memorial Hitachi Science and Technology Foundation; [24686069]; Grants-in-Aid for Scientific ResearchMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [24686069] Funding Source: KAKEN
机构署名:
本校为第一且通讯机构
院系归属:
机械工程学院
摘要:
We report the synthesis of ceria nano-octahedrons using a simple yet efficient hydrothermal technique free of surfactant and template. A comprehensive microscopic characterization reveals that the nano-octahedrons exposed with eight {1 1 1} planes have shape corners and well-defined edges at the nanoscale. Atomic-resolution imaging uncovers that a couple of atomic layers are disappeared at corner, the atomic density of oxygen is reduced at surface, and there occur stacking faults inside the nano-octahedrons, which should have implications for our understanding of catalytic activity of ceria. W...

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