Aryl acyl peroxides for visible-light induced decarboxylative arylation of quinoxalin-2(1: H)-ones under additive-, metal catalyst-, and external photosensitizer-free and ambient conditions

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成果类型：

期刊论文

作者：

Xie, Long-Yong;Peng, Sha;Yang, Li-Hua;Peng, Cun;Lin, Ying-Wu;...

通讯作者：

He, Wei-Min

作者机构：

[Yang, Li-Hua; He, Wei-Min; Xie, Long-Yong; Peng, Sha; Peng, Cun] Hunan Univ Sci & Engn, Dept Chem & Bioengn, Yongzhou 425100, Peoples R China.

[Lin, Ying-Wu] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.

[Yu, Xianyong] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China.

[Peng, Yu-Yu; Cao, Zhong] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Peoples R China.

通讯机构：

[He, Wei-Min] H

Hunan Univ Sci & Engn, Dept Chem & Bioengn, Yongzhou 425100, Peoples R China.

语种：

英文

期刊：

Green Chemistry

ISSN：

1463-9262

年：

2021

卷：

期：

页码：

374-378

DOI：

10.1039/d0gc02844d

基金类别：

We are grateful for financial support from the Hunan Provincial Natural Science Foundation of China (No. 2020JJ5203 and 2019JJ20008).

机构署名：

本校为其他机构

院系归属：

化学化工学院

摘要：

Aryl radicals were generated for the first time from cheap and easily available aryl acyl peroxides in eco-friendly ethyl acetate under ambient conditions and visible-light illumination in the absence of any additive, metal catalyst, or external photosensitizer. The present arylation of quinoxalin-2(1H)-ones was chemo- and regioselective, and provided good access to various 3-arylquinoxalin-2(1H)-ones. ...

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Aryl acyl peroxides for visible-light induced decarboxylative arylation of quinoxalin-2(1: H)-ones under additive-, metal catalyst-, and external photosensitizer-free and ambient conditions

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