期刊论文

Wang, Xiao-Feng

英文

Journal of Molecular Structure

0022-2860

2011

1004

1-3

26-30

10.1016/j.molstruc.2011.07.002

University of South China [2010XQD13]; Fundacao para a Ciencia e a Tecnologia of PortugalPortuguese Foundation for Science and Technology [SFRH/BPD/44381/2008]

本校为第一且通讯机构

Reaction of Cd(Ac)2, 1,4-diazabicyclo[2.2.2]octane (DABCO) and biphenyl-2,2′-dicarboxylic acid or biphenyl-4,4′-dicarboxylic acid, two new cadmium complexes, namely molecular quadrangle [Cd2(2,2′-BPDC)2(Ac)2(DABCOH)2]·2H2O (1) and one dimension (1-D) chain [Cd(Ac)2(DABCO)(H2O)]n·2nH2O (2), have been synthesized and characterized by elemental analysis, IR spectroscopy and X-ray crystallography. The solution–gel–solution transformation course to crystallize 2 was captured. Through the alternately hydrogen bonds between coordinated Ac− and...