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Enhancement of Electrochemical Performance by the Oxygen Vacancies in Hematite as Anode Material for Lithium-Ion Batteries

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成果类型:
期刊论文
作者:
Zeng, Peiyuan;Zhao, Yueying;Lin, Yingwu;Wang, Xiaoxiao;Li, Jianwen;...
通讯作者:
Fang, Zhen
作者机构:
[Li, Jianwen; Fang, Zhen; Zeng, Peiyuan; Wang, Xiaoxiao; Wang, Wanwan; Zhao, Yueying] Anhui Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Mol Solids, Minist Educ,Ctr Nano Sci & Technol, Wuhu 241000, Peoples R China.
[Lin, Yingwu] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
[Fang, Zhen] East Beijing Rd 1, Wuhu, Anhui, Peoples R China.
通讯机构:
[Fang, Zhen] A
[Fang, Zhen] E
Anhui Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Mol Solids, Minist Educ,Ctr Nano Sci & Technol, Wuhu 241000, Peoples R China.
East Beijing Rd 1, Wuhu, Anhui, Peoples R China.
语种:
英文
关键词:
Hematite;Oxygen vacancies;Calcination;Lithium-ion batteries
期刊:
Nanoscale Research Letters
ISSN:
1931-7573
年:
2017
卷:
12
期:
1
页码:
1-9
基金类别:
Natural Science Foundation of China (NSFC)National Natural Science Foundation of China (NSFC) [21101091, 21171007, 21671005]; Programs for Science and Technology Development of Anhui Province [1501021019]
机构署名:
本校为其他机构
院系归属:
化学化工学院
摘要:
The application of hematite in lithium-ion batteries (LIBs) has been severely limited because of its poor cycling stability and rate performance. To solve this problem, hematite nanoparticles with oxygen vacancies have been rationally designed by a facile sol–gel method and a sequential carbon-thermic reduction process. Thanks to the existence of oxygen vacancies, the electrochemical performance of the as-obtained hematite nanoparticles is greatly enhancing. When used as the anode material in LIBs, it can deliver a reversible capacity of 1252 mAh g−1at 2 C after 400&...

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