As a cathode material for proton-conducting SOFCs (H-SOFCs), a novel MnCo1.9Sb0.1O4 (MCSO) spinel material was suggested. The MCSO material was effectively produced, and it demonstrated excellent phase stability at elevated temperatures and chemical stability against CO2 and H2O. Doping Sb into the MnCo2O4 (MCO) allowed for enhanced proton diffusion and surface exchange, as evidenced by electrical conductivity relaxation tests. In addition, an oxygen-vacancy-rich surface was developed for the MCSO material, resulting in the possibility of a high cathode oxygen reduction reaction activity. The ...