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A new and robust MnCo1.9Sb0.1O4 spinel cathode for proton-conducting solid oxide fuel cells

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成果类型:
期刊论文
作者:
Li, Yufeng;Gu, Yueyuan;Yu, Shoufu;Xu, Yangsen;Bi, Lei
通讯作者:
Xu, YS
作者机构:
[Gu, Yueyuan; Yu, Shoufu; Xu, Yangsen; Bi, Lei; Li, Yufeng] Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Peoples R China.
通讯机构:
[Xu, YS ] U
Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
Cathode;Proton-conducting oxides;SOFCs
期刊:
International Journal of Hydrogen Energy
ISSN:
0360-3199
年:
2024
卷:
50
页码:
134-144
基金类别:
National Natural Science Foundation of China [51972183]; Hundred Youth Talents Program of Hunan; Startup Funding for Talents at University of South China
机构署名:
本校为第一且通讯机构
摘要:
As a cathode material for proton-conducting SOFCs (H-SOFCs), a novel MnCo1.9Sb0.1O4 (MCSO) spinel material was suggested. The MCSO material was effectively produced, and it demonstrated excellent phase stability at elevated temperatures and chemical stability against CO2 and H2O. Doping Sb into the MnCo2O4 (MCO) allowed for enhanced proton diffusion and surface exchange, as evidenced by electrical conductivity relaxation tests. In addition, an oxygen-vacancy-rich surface was developed for the MCSO material, resulting in the possibility of a high cathode oxygen reduction reaction activity. The ...

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