期刊论文

Hu, Kongqiu;Shi, Weiqun

英文

INORGANIC CHEMISTRY

0020-1669

2021

60

19

14535-14539

10.1021/acs.inorgchem.1c02082

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [22076187, 22076186]; National Science Fund for Distinguished Young ScholarsNational Natural Science Foundation of China (NSFC)National Science Fund for Distinguished Young Scholars [21925603]

本校为其他机构

Herein we present a new metalloligand, Th(6)L(12) [IHEP-10; L = 4-pyrazolecarboxylic acid (H(2)PyC)], which can be used to generate a novel multicomponent heterometallic metal-organic framework (MOF), [[Cu(3)(μ(3)-OH)(NO(3))(H(2)O)(2)](2)Th(6)(μ(3)-O)(4)(μ(3)-OH)(4)(PyC)(6)(HPyC)(6)(H(2)O)(6)](NO(3))(2) (IHEP-11), through further assembly with second [Cu(3)(μ(3)-OH)(PyC)(3)] clusters. In IHEP-11, six Cu(3) clusters are connected by six NO(3)(-) anions to form an unprecedented annular Cu(18) cluster, which can be viewed as a 12-connected nod...