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Surface Microstructure Engineering for Enhancing Li-Ion Diffusion and Structure Stability of Ni-Rich Cathode Materials

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成果类型:
期刊论文
作者:
Zhuo, Huanming;Zhao, Shuangshuang;Xu, Ruijie;Zhou, Lu;Li, Ye;...
通讯作者:
Tao, YQ
作者机构:
[Zhou, Lu; Xu, Ruijie; Li, Ye; Zhuo, Huanming; Peng, Yuehuan; Zhao, Shuangshuang; Rao, Xuelong; Tao, Yuqiang] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
[Ou, Xing] Cent South Univ, Sch Met & Environm, Changsha 410083, Peoples R China.
通讯机构:
[Tao, YQ ] U
Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
lithium-ion battery;Ni-rich cathodes;heterojunction construction;diffusion kinetics;interfacial stability
期刊:
Nanomaterials
ISSN:
2079-4991
年:
2025
卷:
15
期:
15
页码:
1144-
基金类别:
Conceptualization, X.O. and Y.T.; methodology, X.O. and Y.T.; software, H.Z., S.Z., R.X., and Y.L.; validation, Y.P. and X.R.; formal analysis, S.Z.; investigation, H.Z. and S.Z.; resources, X.O.; data curation, H.Z. and S.Z.; writing—original draft preparation, H.Z. and S.Z.; writing—review and editing, Y.T.; visualization, L.Z.; supervision, Y.T.; project administration, Y.T.; funding acquisition, Y.T. All authors have read and agreed to the published version of the manuscript. This research is supported by the Natural Science Foundation of Hunan Province (2018JJ3447).
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
Surface microstructure of grains vastly decides the electrochemical performance of nickel-rich oxide cathodes, which can improve their interfacial kinetics and structural stability to realize their further popularization. Herein, taking the representative LiNi(0.8)Co(0.15)Al(0.05)O(2) (NCA) materials as an example, a surface heterojunction structure construction strategy to enhance the interface characteristics of high-nickel materials by introducing interfacial ZnO sites has been designed (NCA@ZnO). Impressively, this heterointerface creates a strong built-in electric field, which significant...

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