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Preparation of novel polyvinyl alcohol–carbon nanotubes containing imidazolyl ionic liquid/chitosan hydrogel for highly efficient uranium extraction from seawater

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成果类型:
期刊论文
作者:
Luo, Kaiwen;Wang, Qingliang;Xin, Qi;Lei, Zhiwu;Hu, Eming;...
通讯作者:
Wang, HQ
作者机构:
[Wang, HQ; Wang, Hongqiang; Wang, Qingliang; Luo, Kaiwen; Xin, Qi; Hu, Eming; Lei, Zhiwu] Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Peoples R China.
[Wang, Hongqing] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
[Liang, Feng] Henan Univ Urban Construct, Sch Municipal & Environm Engn, Henan Key Lab Water Pollut Control & Rehabil Techn, Pingdingshan 467036, Peoples R China.
通讯机构:
[Wang, HQ ] U
Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
Adsorption;Hydrogel;Ionic liquid;Selectivity;Uranium
期刊:
International Journal of Biological Macromolecules
ISSN:
0141-8130
年:
2024
卷:
258
期:
Pt 1
页码:
128751
基金类别:
Natural Science Foundation of Hunan Province1 [2020JJ4518]; Natural Science Foundation of Hunan Province [2021JJ50013]; Key Project of the Education Department of Hunan Province [18A231]; Open Fund of the State Key Laboratory of Nuclear Resources and Environment [2020NRE01]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
A novel polyvinyl alcohol-carbon nanotube containing an imidazolyl ionic liquid/chitosan composite hydrogel (termed CBCS) was prepared for highly selective uranium adsorption from seawater. The results show that CBCS has good adsorption properties for uranium within the pH range of 5.0-8.0. Kinetics and thermodynamics experiments show that the theoretical maximum adsorption capacity of CBCS to U(VI) is 496.049mg/g (288K, pH=6.0), indicating a spontaneous exothermic reaction. Mechanism analysis shows that the hydroxyl group, amino group, and CN bond on the surface of CBCS directly participate i...

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