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成果类型:
期刊论文
作者:
Xu, Yufen;Wang, Yanfei
通讯作者:
Wang, YF
作者机构:
[Wang, Yanfei; Xu, Yufen] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
通讯机构:
[Wang, YF ] U
Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
Triphenyl phosphate (TPP);Bis (diphenyl phosphate) imine (Htpop);U(VI);Adsorption
期刊:
Progress in Nuclear Energy
ISSN:
0149-1970
年:
2023
卷:
166
页码:
104957
基金类别:
Credit authors statement Yufen Xu: Investigation, Visualization, Formal analysis, Data curation, Methodology, Writing – original draft, Validation. Yanfei Wang: Conceptualization, Supervision, acquisition, Writing – review & editing.
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
Bis(diphenyl phosphate) imine(Htpop) was synthesized as an adsorbent for the effective removal of U(VI) from aqueous solutions using triphenyl phosphate(TPP) as the starting material. Htpop possesses notable polarity, characterized by the presence of -P--O(phosphoryl) and -N-H(imino) functional groups, along with other bulky substituents. It has the capability to form chelates with metal ions, thus enabling the removal of radionuclide U (VI) from aqueous solution. The overall adsorption experiment shows that both phosphoryl and imino groups interact with uranyl ions, and the removal rate reach...

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