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TiO2-induced electronic change in traditional La0.5Sr0.5MnO3-delta cathode allows high performance of proton-conducting solid oxide fuel cells

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成果类型:
期刊论文
作者:
Li, Yufeng;Yu, Shoufu;Dai, Hailu;Xu, Yangsen*;Bi, Lei
通讯作者:
Xu, Yangsen;Bi, L
作者机构:
[Yu, Shoufu; Xu, Yangsen; Bi, Lei; Li, Yufeng] Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Peoples R China.
[Dai, Hailu] Yancheng Inst Technol, Sch Mat Sci & Engn, Yancheng 224051, Peoples R China.
通讯机构:
[Xu, YS; Bi, L ] U
Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
La0.5Sr0.5MnO3-delta;cathode;proton conductor;solid oxide fuel cells
期刊:
中国科学:材料科学(英文版)
ISSN:
2095-8226
年:
2023
卷:
66
期:
9
页码:
3475-3483
基金类别:
National Natural Science Foundation of China [52272216, 51972183]; Hundred Youth Talents Program of Hunan; Startup Funding for Talents at the University of South China
机构署名:
本校为第一且通讯机构
摘要:
Sr-doped LaMnO3, as one of the most successful cathodes for solid oxide fuel cells (SOFCs), can effectively function at high temperatures. However, its cathode kinetics considerably decreases with decreasing temperature, rendering it unsuitable for SOFCs operating at intermediate temperatures. In this study, La0.5Sr0.5MnO3-delta(LSM) is coated with TiO2 to create the LSM + TiO2 cathode. TiO2 is shown to modify the electronic structure at the LSM/TiO2 interface, allowing for charge accumulation for the O atoms at the interface. The activated O atoms enhance the formation of oxygen vacancies, wh...

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