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Efficient removal of uranium from groundwater by phosphorylated chitosan-supported nano iron composites

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成果类型:
期刊论文
作者:
Wen, Siqian;Wang, Hongqiang;Wang, Qingliang;Xin, Qi;Hu, Eming;...
通讯作者:
Qingliang Wang
作者机构:
[Wang, Hongqiang; Hu, Fang; Wang, Qingliang; Xin, Qi; Wen, Siqian; Hu, Eming; Lei, Zhiwu] Univ South China, Sch Resource & Environm & Safety Engn, Hengyang 421001, Peoples R China.
[Wang, Qingliang] Univ South China, Cooperat Innovat Ctr Nucl Fuel Cycle Technol & Eq, Hengyang 421001, Peoples R China.
通讯机构:
[Qingliang Wang] S
School of Resource and Environment and Safety Engineering, University of South China, Hengyang, China<&wdkj&>Cooperative Innovation Center for Nuclear Fuel Cycle Technology and Equipment, University of South China, Hengyang, China
语种:
英文
关键词:
Adsorption;Reduction;Chitosan;Nano iron;Phosphorylation
期刊:
Journal of Radioanalytical and Nuclear Chemistry
ISSN:
0236-5731
年:
2022
卷:
331
期:
12
页码:
5529-5538
基金类别:
Natural Science Foundation of Hunan Province [2020JJ4518]; Key Project of Education Department of Hunan Province [18A231]; Open Fund of State Key Laboratory of Nuclear Resources and Environment [2020NRE01]
机构署名:
本校为第一机构
院系归属:
机械工程学院
摘要:
In this study, a new type of phosphorylated chitosan-supported nano iron (CSP/Fe-0) composite material. CSP/Fe-0 had a high adsorption rate (99.25%) and a maximum adsorption capacity (627.34 mg g(-1)) when the conditions were pH = 6, 308.15 K and 12 h. CSP/Fe-0 had a specific surface area of CSP/Fe-0 was 6.02 m(2) g(-1), and has a mesoporous structure with more active sites (average pore size is 9.67 nm). The primary mechanism may be the complexation of U(VI) with abundant -OH, -NH2, P=O on the surface of the material and the reduction of nanoscale zero-valent iron. Therefore, it is indicated ...

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