期刊论文

Tan, N.

中文

中山大学学报(自然科学版)(中英文)

0529-6579

2008

47

4

59-62

国家863计划资助项目（2006AA09Z422）； 国家自然科学基金资助项目（20072058）； 广东省自然科学基金重点资助项目（021732）； 南华大学博士启动基金资助项目（5-2007-XQD-002）；

本校为第一且通讯机构

从南海红树林内源真菌Fusarium sp. ZZF51的培养液中分离得到一金属络合物(1),通过波谱数据和单晶衍射数据解析其结构为二(5-丁基-2-吡啶甲酸-N1,O2)合铜(Ⅱ)。为提高其产量,研究了Cu(Ⅱ)对络合物(1)产量和菌株生长的影响,结果表明:在参与真菌Fusarium sp. ZZF51代谢活动的过程中,Cu(Ⅱ)能显著促使络合物(1)的产生,但对真菌的生长影响甚微.

A metal complex (1), named as bis (5-butyl-2-pyridinecarboxylato-N1, 02)-copper, was first found in the nature. It was isolated from the culture media of a mangrove entophytic fungus Fusarium sp. ZZF51 from the South China Sea coast. Its structure was characterized using spectroscopic methods and single crystal X-ray diffraction analysis. The relation between the amount of CuCl2 and the fungus ZZF51 growth was investigated in order to improve the output of complex (1). The result indicated CuCl2 showed great efficiency for producing...