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Fine tuning of pore size in metal-organic frameworks for superior removal of U(vi) from aqueous solution

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成果类型:
期刊论文
作者:
Fu, Tianyu;Liu, Hongjuan;Wang, Xinyi;Liu, Yingjiu
通讯作者:
Liu, HJ
作者机构:
[Fu, Tianyu; Wang, Xinyi; Liu, Hongjuan; Liu, HJ] Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Peoples R China.
[Liu, Yingjiu] Univ South China, Hunan Prov Key Lab Pollut Control & Resources Reus, Hengyang 421001, Peoples R China.
[Liu, Hongjuan; Liu, HJ] Univ South China, Key Discipline Lab Natl Def Biotechnol Uranium Min, Hengyang 421001, Peoples R China.
通讯机构:
[Liu, HJ ] U
Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Peoples R China.
Univ South China, Key Discipline Lab Natl Def Biotechnol Uranium Min, Hengyang 421001, Peoples R China.
语种:
英文
期刊:
NEW JOURNAL OF CHEMISTRY
ISSN:
1144-0546
年:
2024
卷:
48
期:
14
页码:
6211-6220
基金类别:
Natural Science Foundation of Hunan Province [2021JJ30563, 2018JJ3420]; Natural Science Foundation of Hunan Province
机构署名:
本校为第一且通讯机构
院系归属:
土木工程学院
核科学技术学院
核资源工程学院
摘要:
The pore structure of metal-organic frameworks (MOFs) is crucial to their adsorption performance, and it is still a challenge to precisely control the pore size to realize superior removal of uranium. The pore size of MOF-A, MOF-B and MOF-C was fine-tuned by using three organic chains with different lengths (fumaric acid, terephthalic acid and naphthalene dicarboxylic acid, respectively). The synthesized MOF-A, MOF-B and MOF-C had ordered increase in pore sizes with 3.8 & Aring;, 5.7 & Aring; and 7.6 & Aring;, respectively. Pore size of 7.6 & Aring; in MOF-C was a little larger than the geomet...

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