Complexation and enantioselectivity of novel bridge-like uranyl-2-((1Z,9Z)-9-(2-Hydroxyphenyl)-3,5,6,8-tetrahydrobenzo[h][1,4,7,1 0] dioxadiazacyclododecin-2-yl)-5-methoxyphenol with chiral organophosphorus pesticide enantiomers of R/S-malathions

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成果类型：

期刊论文

作者：

Tao, Xuebing;Yang, Rong;Xiao, Yang;Liao, Lifu;Xiao, Xilin;...

通讯作者：

Nie, Changming(Niecm196132@163.com)

作者机构：

[Yang, Rong; Tao, Xuebing; Xiao, Xilin; Liao, Lifu; Nie, Changming; Xiao, Yang] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.

[Yang, Rong; Tao, Xuebing; Nie, Changming; Xiao, Yang] Key Lab Hunan Prov Design & Applicat Nat Actinide, Hengyang 421001, Peoples R China.

通讯机构：

[Changming Nie] S

School of Chemistry and Chemical Engineering, University of South China, Hengyang, People’s Republic of China<&wdkj&>Key Laboratory of Hunan Province for Design and Application of Natural Actinide Complexes, Hengyang, People’s Republic of China

语种：

英文

关键词：

Bridge-like uranyl-salophen;R/S-malathions;chiral organophosphorus pesticide;density functional theory;enantioselectivity

期刊：

Environmental Technology

ISSN：

0959-3330

年：

2022

卷：

期：

页码：

3378-3389

DOI：

10.1080/09593330.2021.1921055

基金类别：

Hunan Provincial Innovation Foundation for Postgraduate [CX2018B584]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11475079]; Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [2020JJ6049]

机构署名：

本校为第一机构

院系归属：

化学化工学院

摘要：

Designing new uranyl complexes with enantioselectivity is of great significance for the identification and separation of enantiomers of chiral pesticides. In this paper, a new asymmetric rigid uranyl-2-((1Z,9Z)-9-(2-Hydroxyphenyl)-3,5,6,8-tetrahydrobenzo[h][1,4,7,10] dioxadiaza-cyclododecin-2-yl)-5-methoxyphenol(Uranyl-HTDM) was designed, we used Uranyl-HTDM as a receptor to selectively coordinate with the guests of the chiral organophosphorus pesticide R/S-malathions(R/S-MLTs) to explore the receptor's enatioselectivity recognition of the chir...

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Complexation and enantioselectivity of novel bridge-like uranyl-2-((1Z,9Z)-9-(2-Hydroxyphenyl)-3,5,6,8-tetrahydrobenzo[h][1,4,7,1 0] dioxadiazacyclododecin-2-yl)-5-methoxyphenol with chiral organophosphorus pesticide enantiomers of R/S-malathions

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