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Computational design and fabrication of core-shell magnetic molecularly imprinted polymer for dispersive micro-solid-phase extraction coupled with high-performance liquid chromatography for the determination of rhodamine 6G

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成果类型:
期刊论文
作者:
Xie, Jin;Xie, Jie;Deng, Jian*;Fang, Xiangfang;Zhao, Haiqing;...
通讯作者:
Deng, Jian
作者机构:
[Zhao, Haiqing; Wang, Hongjuan; Deng, Jian; Qian, Duo; Xie, Jin; Fang, Xiangfang] Univ South China, Sch Chem & Chem Engn, Hengyang, Hunan, Peoples R China.
[Xie, Jie] China Agr Univ, Coll Vet Med, Beijing, Peoples R China.
[Xie, Jie] China Agr Univ, State Key Lab Agrobiotechnol, Beijing, Peoples R China.
通讯机构:
[Deng, Jian] U
Univ South China, Sch Chem & Chem Engn, Hengyang, Hunan, Peoples R China.
语种:
英文
关键词:
Dispersive micro-solid-phase extraction;High-performance liquid chromatography;Magnetic surface molecularly imprinted polymers;Rhodamine 6G
期刊:
JOURNAL OF SEPARATION SCIENCE
ISSN:
1615-9306
年:
2016
卷:
39
期:
12
页码:
2422-2430
基金类别:
Hunan Technology Department Foundation, China [2013FJ3028]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
A novel core–shell magnetic nano-adsorbent with surface molecularly imprinted polymer coating was fabricated and then applied to dispersive micro-solid-phase extraction followed by determination of rhodamine 6G using high-performance liquid chromatography. The molecularly imprinted polymer coating was prepared by copolymerization of dopamine and m-aminophenylboronic acid (functional monomers), in the presence of rhodamine 6G (template). The selection of the suitable functional monomers was based on the interaction between different monomers and the template using the density functional t...

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