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Green synthesis of citric acid-crosslinked β-cyclodextrin for highly efficient removal of uranium(VI) from aqueous solution

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成果类型:
期刊论文
作者:
Li, Wei;Liu, Huijun*;Li, Liuxing;Liu, Kai;Liu, Juan;...
通讯作者:
Liu, Huijun
作者机构:
[Tang, Ting; Liu, Juan; Liu, Huijun; Li, Wei; Jiang, Wenkang; Li, Liuxing; Liu, Kai] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
[Liu, Huijun; Li, Wei] Univ South China, Hunan Key Lab Design & Applicat Actinide Complexe, Hengyang 421001, Hunan, Peoples R China.
通讯机构:
[Liu, Huijun] U
Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
Univ South China, Hunan Key Lab Design & Applicat Actinide Complexe, Hengyang 421001, Hunan, Peoples R China.
语种:
英文
关键词:
beta cyclodextrin;citric acid;polymer;potassium dihydrogen phosphate;uranium;adsorption;aqueous solution;Article;cross linking;Fourier transform infrared spectroscopy;heavy metal removal;mathematical analysis;pH;recycling;scanning electron microscopy;synthesis;thermodynamics;thermogravimetry;ultraviolet spectrophotometry;waste water management;X ray diffraction
期刊:
Journal of Radioanalytical and Nuclear Chemistry
ISSN:
0236-5731
年:
2019
卷:
322
期:
3
页码:
2033-2042
基金类别:
We are grateful to acknowledge the support of this work from Nature Science Foundation of China (No. 11375084), the Nature Science Foundation of Hunan (No. 2017JJ4046). We are grateful to acknowledge the support of this work from Nature Science Foundation of China (No. 11375084), the Nature Science Foundation of Hunan (No. 2017JJ4046). Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
In this paper, a green synthesized citric acid-crosslinked β-cyclodextrin polymer (CA-β-CD) was applied in removing uranium from aqueous solutions. Citric acid acts not only as cross-linker but also as functional groups for providing adsorption sites. The adsorption properties by varying experimental conditions were carried out by batch tests. The maximum adsorption capacity could reach 150mgg−1. Adsorption process was fitted better with the pseudo-second-order and Freundlich model. Thermodynamic studies proved that adsorption process was sp...

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