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Green synthesis of citric acid-crosslinked beta-cyclodextrin for highly efficient removal of uranium(VI) from aqueous solution

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成果类型:
期刊论文
作者:
Li, Wei;Liu, Huijun*;Li, Liuxing;Liu, Kai;Liu, Juan;...
通讯作者:
Liu, Huijun
作者机构:
[Tang, Ting; Liu, Juan; Liu, Huijun; Li, Wei; Jiang, Wenkang; Li, Liuxing; Liu, Kai] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
[Liu, Huijun; Li, Wei] Univ South China, Hunan Key Lab Design & Applicat Actinide Complexe, Hengyang 421001, Hunan, Peoples R China.
通讯机构:
[Liu, Huijun] U
Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
Univ South China, Hunan Key Lab Design & Applicat Actinide Complexe, Hengyang 421001, Hunan, Peoples R China.
语种:
英文
关键词:
beta-cyclodextrin;Citric acid;Polymer;Uranium;Adsorption
期刊:
Journal of Radioanalytical and Nuclear Chemistry
ISSN:
0236-5731
年:
2019
卷:
322
期:
3
页码:
2033-2042
基金类别:
Nature Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11375084]; Nature Science Foundation of Hunan [2017JJ4046]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
In this paper, a green synthesized citric acid-crosslinked beta-cyclodextrin polymer (CA-beta-CD) was applied in removing uranium from aqueous solutions. Citric acid acts not only as cross-linker but also as functional groups for providing adsorption sites. The adsorption properties by varying experimental conditions were carried out by batch tests. The maximum adsorption capacity could reach 150 mg g(-1). Adsorption process was fitted better with the pseudo-second-order and Freundlich model. Thermodynamic studies proved that adsorption process was spontaneous and endothermic. More significant...

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