Enantioselective determination of S-ornidazole by using carbon paste electrode modified with boron-embedded conductive copolymer-polysiloxane-based molecularly imprinted hybrid film

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成果类型：

期刊论文

作者：

Wang, Hongjuan;Qian, Duo;Xiao, Xilin*;He, Bo;Gao, Shuqin;...

通讯作者：

Xiao, Xilin;Deng, Jian

作者机构：

[Xiao, XL; Deng, Jian; Wang, Hongjuan; Xiao, Xilin; Qian, Duo; Liao, Lifu; He, Bo] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.

[Gao, Shuqin] Univ South China, Sch Med, Hengyang 421001, Hunan, Peoples R China.

[Shi, Han] Bur Anim Husb & Fisheries, Shaodong 422800, Hunan, Peoples R China.

通讯机构：

[Xiao, XL; Deng, J] U

Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.

语种：

英文

关键词：

S-ornidazole;Enantioselective determination;Molecularly imprinted hybrid film;Electrochemical sensor

期刊：

Electrochimica Acta

ISSN：

0013-4686

年：

2017

卷：

246

页码：

338-347

DOI：

10.1016/j.electacta.2017.06.064

基金类别：

Hunan Technology Department Foundation, China [2013FJ3028]; Innovation Foundation for Postgraduate from University of South China [2016XCX08]; Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [31200140, 11475079]; Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education MinistryScientific Research Foundation for the Returned Overseas Chinese Scholars [2015jyb02]

机构署名：

本校为第一且通讯机构

院系归属：

化学化工学院

医学院

摘要：

Highly selective determination of enantiomers by electrochemical sensors with simple recognition elements is of great interest in pharmaceutics, biochemistry and medical fields. The present work developed an innovative electrochemical sensor, which based on boron-embedded molecularly imprinted hybrid film (B-MIHF) modified carbon paste electrode (CPE), for enantioselective determination of S-ornidazole (S-ONZ). A boron-embedded conductive copolymer was firstly electro polymerized on carbon paste electrode (CPE), and then molecularly imprinted polysiloxanes (MIP) were hydrolyzed and condensed o...

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Enantioselective determination of S-ornidazole by using carbon paste electrode modified with boron-embedded conductive copolymer-polysiloxane-based molecularly imprinted hybrid film

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