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Aryl Diazonium-Assisted Amidoximation of MXene for Boosting Water Stability and Uranyl Sequestration via Electrochemical Sorption

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成果类型:
期刊论文
作者:
Zhang, Pengcheng;Wang, Lin;Huang, Zhiwei;Yu, Jipan;Li, Zijie;...
通讯作者:
Shi, Weiqun
作者机构:
[Huang, Zhiwei; Yuan, Liyong; Shi, Weiqun; Yu, Jipan; Zhang, Pengcheng; Mei, Lei; Yin, Taiqi; Deng, Hao; Li, Zijie; Wang, Lin] Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China.
[Wang, Hongqing; Zhang, Pengcheng] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
[Gibson, John K.] Lawrence Berkeley Natl Lab, Chem Sci Div, Berkeley, CA 94720 USA.
[Zheng, Lirong] Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China.
[Chai, Zhifang] Chinese Acad Sci, Ningbo Inst Ind Technol, Engn Lab Adv Energy Mat, Ningbo 315201, Peoples R China.
通讯机构:
[Shi, Weiqun] C
Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China.
语种:
英文
关键词:
MXene;amidoxime group;diazonium salt;uranium capture;electrosorption
期刊:
ACS Applied Materials & Interfaces
ISSN:
1944-8244
年:
2020
卷:
12
期:
13
页码:
15579-15587
基金类别:
This work was supported by the Natural Science Foundation of China (Grants 11675192, 21836001, 21777161, 11975016, and 21577144) and the National Science Fund for Distinguished Young Scholars (Grant 21925603). The Science Challenge Project (TZ2016004) is also acknowledged. We are grateful to the staff of Beijing Synchrotron Radiation Facility (BSRF) for EXAFS and XANES measurement.
机构署名:
本校为其他机构
院系归属:
化学化工学院
摘要:
Despite that two-dimensional transition metal carbides and carbonitrides (MXenes) are burgeoning candidates for remediation of environmental pollutants, the construction of robust functionalized MXene nanosheets with a high affinity for target heavy metal ions and radionuclides remains a challenge. Here we report the successful placement of amidoxime chelating groups on Ti3C2Tx MXene surface by diazonium salt grafting. The introduction of amidoxime functional groups significantly enhances the selectivity of Ti3C2Tx nanosheets for uranyl ions an...

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