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Enhanced performance in uranium extraction by the synergistic effect of functional groups on chitosan-based adsorbent

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成果类型:
期刊论文
作者:
Xin, Qi;Wang, Qingliang;Gan, Jiali;Lei, Zhiwu;Hu, Eming;...
通讯作者:
Hongqiang Wang
作者机构:
[Wang, Hongqiang; Wang, Qingliang; Gan, Jiali; Xin, Qi; Hu, Eming; Lei, Zhiwu] Univ South China, Sch Resource & Environm & Safety Engn, Hengyang 421001, Peoples R China.
[Wang, Hongqiang] East China Univ Technol, State Key Lab Nucl Resources & Environm, Nanchang 330013, Peoples R China.
[Wang, Hongqing] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
通讯机构:
[Hongqiang Wang] S
School of Resource & Environment and Safety Engineering, University of South China, Hengyang 421001, China<&wdkj&>State Key Laboratory of Nuclear Resources and Environment (East China University of Technology), Nanchang 330013, China
语种:
英文
关键词:
Chitosan;Phosphate group;Selectivity;Uranium;Vanadium
期刊:
Carbohydrate Polymers
ISSN:
0144-8617
年:
2023
卷:
300
页码:
120270
基金类别:
This work was supported by Natural Science Foundation of Hunan Province (grant number: 2020JJ4518 ), Key Project of Education Department of Hunan Province (grant number: 18A231 ), Open Fund of State Key Laboratory of Nuclear Resources and Environment (grant number: 2020NRE01 ). And thanks to Dongtai City Spirulina Bio-Engineering Co., LTD. for providing the Chlorella pyrenoidosa for free for this study.
机构署名:
本校为第一机构
院系归属:
化学化工学院
摘要:
In this study, a novel sponge phosphoric acid functionalized porous composite adsorbent (named SPCCHC) was prepared from chitosan and chlorella hydrothermal charcoal. Kinetics and thermodynamics experiments showed that the theoretical maximum adsorption capacity of SPCCHC to U(VI) is 579.27 mg/g (288 K, pH = 6.5), indicating a spontaneous exothermic reaction. SPCCHC showed good adsorption selectivity for uranium in the adsorption studies of simulated seawater and a mixed solution of uranium–vanadium. The characterization of SPCCHC before and a...

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