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Two-phase activated colorimetric and ratiometric fluorescent sensor for visual detection of phosgene via AIE coupled TICT processes

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成果类型:
期刊论文
作者:
Hu, Qinghua*;Gong, Tao;Mao, Yu;Yin, Qiang;Wang, Yuyuan;...
通讯作者:
Hu, Qinghua;Wang, Hongqing
作者机构:
[Wang, Hongqing; Gong, Tao; Hu, Qinghua; Mao, Yu; Wang, Yuyuan; Yin, Qiang] Univ South China, Hunan Key Lab Design & Applicat Actinide Complexe, Sch Chem & Chem Engn, 28 Changsheng West Rd, Hengyang 421001, Hunan, Peoples R China.
通讯机构:
[Hu, Qinghua; Wang, Hongqing] S
School of Chemistry and Chemical Engineering, Hunan Key Laboratory for the Design and Application of Actinide Complexes, University of South China, 28 Changsheng West Road, Hengyang, Hunan 421001, PR China. Electronic address:
语种:
英文
关键词:
Fluorescent sensors;Phosgene;Ratiometric;AIE and TICT;Colorimetric
期刊:
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
ISSN:
1386-1425
年:
2021
卷:
253
页码:
119589
基金类别:
CRediT authorship contribution statement Qinghua Hu: Formal analysis, acquisition, Writing - review & editing. Tao Gong: Investigation, Writing - original draft, Formal analysis. Yu Mao: Software. Qiang Yin: Software, Formal analysis. Yuyuan Wang: Resources. Hongqing Wang: Conceptualization, Methodology, acquisition, Supervision, Validation, Writing - review & editing.
机构署名:
本校为第一机构
院系归属:
化学化工学院
摘要:
In this paper, we specifically designed and synthesized an excellent colorimetric and ratiometric fluorescent sensor DPA-CI for rapid and convenient detection of the highly toxic phosgene. DPA-CI was developed by incorporated a diphenylamine (DPA) and a 2-imine-3-benzo[d]imidazole as the enhanced push-pull electronic structure into the coumarin fluorophore matrix. The sensor DPA-CI towards phosgene sensing exhibited both visible colorimetric and ratiometric fluorescent color change in solution and in gaseous conditions with TICT and AIE mechanism respectively, which can be easily distinguished...

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