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Properties and characterization of a metakaolin phosphate acid–based geopolymer synthesized in a humid environment

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成果类型:
期刊论文
作者:
Dong, Teng;Xie, Shuibo*;Wang, Jingsong;Chen, Zhenfu;Liu, Qing
通讯作者:
Xie, Shuibo
作者机构:
[Dong, Teng; Wang, Jingsong; Xie, Shuibo; Chen, Zhenfu; Liu, Qing] Univ South China, Sch Civil Engn, Hengyang 421001, Hunan, Peoples R China.
[Dong, Teng; Xie, Shuibo] Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Hunan, Peoples R China.
通讯机构:
[Xie, Shuibo] U
Univ South China, Sch Civil Engn, Hengyang 421001, Hunan, Peoples R China.
Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Hunan, Peoples R China.
语种:
英文
关键词:
Aluminum;Aluminum compounds;Geopolymers;Inorganic polymers;Leaching;Molar ratio;Phosphoric acid;Pore size;Calcined kaolins;Capillary pores;Geopolymer;Geopolymerization;High-humidity environment;Humid environment;Metakaolins;Structural unit;Silicon
期刊:
Journal of the Australian Ceramic Society
ISSN:
2510-1560
年:
2020
卷:
56
期:
1
页码:
175-184
基金类别:
The authors gratefully acknowledge the Research Foundation of Education Bureau of Hunan Province, China (Grant No. 18K075 ) and the National Natural Science Foundation of China (Grant No. 51678286).
机构署名:
本校为第一且通讯机构
院系归属:
土木工程学院
摘要:
To synthesize a metakaolin phosphate acid-based geopolymer (PAG), calcined kaolin and phosphoric acid solutions with phosphorus-to-aluminium molar ratios (P/Al) of 0.6 to 1.0 were prepared. Fresh PAG was cured in a high-humidity environment at 50°C for 7days. High humidity is helpful for generating AlPO4 during the geopolymerization of PAG. Si and Al are depolymerized from metakaolin upon attack of H3PO4, and the amounts of leached Si and Al are directly proportional to P/Al. Leached Al increases with time, while leached Si decreases and then ...

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